Gas-Phase Reactions of Nickel and Nickel Oxide Clusters with Nitrogen Oxides. 3. Reactions of Cations with Nitric Oxide

W. D. Vann; R. C. Bell; A. W. Castleman Jr.

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Gas-Phase Reactions of Nickel and Nickel Oxide Clusters with Nitrogen Oxides. 3. Reactions of Cations with Nitric Oxide

机译：镍和氧化镍团簇与氮氧化物的气相反应。 3.阳离子与一氧化氮的反应

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A fast flow reactor-quadrupole mass spectrometer system coupled with a laser vaporization source is used to study the gas-phase reactions of nickel and nickel oxide cluster cations with nitric oxide. Pseudo-first-order bimolecular rate constants are reported for the reactions of NO with nickel and nickel oxide cluster cations and O_2 reactions with nickel cluster cations. The product distributions indicate that several different reaction mechanisms occur between NO and Ni_x~+ and Ni_xO_y~+. Competing processes such as oxidation, NO addition, and replacement of oxygen with nitric oxide are observed to occur. Also, the presence of magic peaks in the distributions indicates unusually stable product cluster species.

机译：快速流反应器-四极杆质谱仪系统与激光汽化源耦合，用于研究镍和镍氧化物簇阳离子与一氧化氮的气相反应。报道了NO与镍和氧化镍簇阳离子的反应和O_2与镍簇阳离子的反应的伪一阶双分子速率常数。产物分布表明NO与Ni_x〜+和Ni_xO_y〜+之间发生了几种不同的反应机理。观察到发生了竞争过程，例如氧化，添加NO和用一氧化氮代替氧气。同样，分布中存在魔术峰表示异常稳定的产品簇物种。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1999年第50期|共5页
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W. D. Vann; R. C. Bell; A. W. Castleman Jr.;
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中图分类物理化学（理论化学）、化学物理学;
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1. Gas-Phase Reactions of Nickel and Nickel Oxide Clusters with Nitrogen Oxides. 3. Reactions of Cations with Nitric Oxide [J] . W. D. Vann, R. C. Bell, A. W. Castleman Jr. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1999,第50期

机译：镍和氧化镍团簇与氮氧化物的气相反应。 3.阳离子与一氧化氮的反应
2. Gas-Phase Reactions of Nickel Oxide Clusters with Nitric Oxide. 1. Formation of Nitrogen Dioxide on Nickel Oxide Cluster Anions [J] . W. D. Vann, R. L. Wagner, A. W. Castleman Jr. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第10期

机译：氧化镍团簇与一氧化氮的气相反应。 1.在氧化镍团簇阴离子上形成二氧化氮
3. Gas-Phase Reactions of Nickel Oxide Clusters with Nitric Oxide. 1. Formation of Nitrogen Dioxide on Nickel Oxide Cluster Anions [J] . W. D. Vann, R. L. Wagner, A. W. Castleman Jr. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第9a12期

机译：氧化镍团簇与一氧化氮的气相反应。 1.在氧化镍团簇阴离子上形成二氧化氮
4. Nickel Oxide Cluster Reactions With Nitric Oxide [C] . W. D. Vann, R. L. Wagner, A. W. Castleman International conference on high temperature materials chemistry . 1997

机译：用一氧化氮氧化镍簇反应
5. Flow tube calibration and infrared product studies using hydrogen and hydroperoxyl gas-phase radical reactions with nitrogen oxides. [D] . Koutros, Christopher C. 2014

机译：流量管校准和红外产品研究，使用氢和氢过氧气相自由基反应与氮氧化物。
6. Oxygen Isotope Labeling Experiments Reveal Different Reaction Sites for the Oxygen Evolution Reaction on Nickel and Nickel Iron Oxides [O] . Dr. Seunghwa Lee, Karla Banjac, Dr. Magalí Lingenfelder, -1

机译：氧同位素标记实验揭示了镍和镍铁氧化物上析氧反应的不同反应部位
7. Reactions of Nitrogen Oxides with Heme Models. Spectral and Kinetic Study of Nitric Oxide Reactions with Solid and Solute FeIII(TPP)(NO3) [O] . -1

机译：氮氧化物与血红素模型的反应。用固体和溶质FeiII（TPP）的一氧化氮反应的光谱和动力学研究（NO3）
8. Laser-Induced Reactions of Nitrogen Fluorides with Nitrogen Oxides. [R] . Merritt, J. A., McDonald, J. K., Kalasinsky, V. F. 1982

机译：激光诱导氟化氮与氮氧化物的反应。

Gas-Phase Reactions of Nickel and Nickel Oxide Clusters with Nitrogen Oxides. 3. Reactions of Cations with Nitric Oxide

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