Photloinduced Electron Transfer and Adduct Formation between C_(60)/C_(70) and Optically Active 1,1'-Binaphthyl-2,2'-diamine

Maged El-Kemary; Mamoru Fujitstuka; Osamu Ito

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Photloinduced Electron Transfer and Adduct Formation between C_(60)/C_(70) and Optically Active 1,1'-Binaphthyl-2,2'-diamine

机译：C_（60）/ C_（70）与旋光1,1'-联萘-2,2'-二胺之间的光致电子转移和加合物形成

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Photoinduced electron transfer and adduct formation between C_(60)/C_(70) and 1,1'-binaphthyl-2,2'-diamine (BNA) have been studied by nanosecond laser flash photolysis and steady-state photolysis as well as circular dichroism measurements. Quantum yields (#PHI#_(et)~T) and rate constants of electron transfer from BNA to the excited triplet state of C_(60)/C_(70) have been determined by observing the transient absorption bands in the near-IR region where the triplet states and anion radicals of fullerenes appear. Compared with the planar naphthylamine moiety, #PHI#_(et)~T values of perpendicular bichromophoric BNA are low because of hindrance of approach to round fullerenes. The formation of an optically active adduct between C_(60) and BNA in a polar solvent was observed upon excitation with light at #lambda# > 330 nm where both C_(60) and BNA are light-absorbing. The reaction mechanism for the optically active adduct formation can be explained as a result of th addition reaction of the N-centered radical formed by deprotonation of BNA~+, which is produced by direct photoejection.

机译：通过纳秒激光闪光光解法和稳态光解法以及环形法研究了C_（60）/ C_（70）与1,1'-联萘-2,2'-二胺（BNA）之间的光诱导电子转移和加合物形成二向色性测量。通过观察近红外的瞬态吸收带，确定了量子产率（#PHI #_（et）〜T）和电子从BNA转移到C_（60）/ C_（70）的激发三重态的速率常数。富勒烯三重态和阴离子自由基出现的区域。与平面的萘胺部分相比，垂直双发色BNA的#PHI #_（et）〜T值较低，这是因为其难以接近圆形富勒烯。在＃lambda＃> 330 nm处用光激发时，观察到极性溶剂中C_（60）和BNA之间形成了光学活性加合物，其中C_（60）和BNA均吸光。光学活性加合物形成的反应机理可以解释为由直接光喷射产生的BNA〜+的去质子化形成的N-中心自由基的加成反应的结果。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1999年第10期|共6页
作者
Maged El-Kemary; Mamoru Fujitstuka; Osamu Ito;
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中图分类物理化学（理论化学）、化学物理学;
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1. Photloinduced Electron Transfer and Adduct Formation between C_(60)/C_(70) and Optically Active 1,1'-Binaphthyl-2,2'-diamine [J] . Maged El-Kemary, Mamoru Fujitstuka, Osamu Ito The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1999,第10期

机译：C_（60）/ C_（70）与旋光1,1'-联萘-2,2'-二胺之间的光致电子转移和加合物形成
2. Characterization of the Charge Transfer between Fullerenes (C_(60)/C_(70)) and N, N, N', N'-Tetra-(p-methyl-phenyl)-4,4'-Diamino-1,1'-Diphenyl Telluride [TPDATe] [J] . He-Ping ZENG Synthetic Metals . 2003,第4期

机译：富勒烯（C_（60）/ C_（70））与N，N，N'，N'-四-（对甲基-苯基）-4,4'-二氨基-1,1'之间的电荷转移的表征-二苯基碲化物[TPDATe]
3. Semiempirical molecular dynamics studies of C_(60)/C_(70) fullerene oxides: C_(60)O, C_(60)O_2 and C_(70)O [J] . Bo-Cheng Wang, Likey Chen, Kuei-Jen Lee, Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 1999,第1期

机译：C_（60）/ C_（70）富勒烯氧化物：C_（60）O，C_（60）O_2和C_（70）O的半经验分子动力学研究
4. Photoinduced Electron-Transfer From Two-Electron Donor to C_(60) and C_(70) [C] . Kenichi Yamanaka, Mamoru Fujitsuka, Osamu Ito, International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters, May 12-17, 2002, Philadelphia . 2002

机译：从两个电子供体向C_（60）和C_（70）的光诱导电子转移
5. Monitoring the Conformation of Benzoapyrene Adducts in the Polymerase Active Site using Fluorescence Resonance Energy Transfer [O] . Thomas D. Christian, Louis J. Romano -1

机译：监测苯并构象在使用荧光共振能量转移的聚合酶活性位点a芘加合物
6. Lattice distortion and energy level structures in doped C_{60} and C_{70} studied with the extended Su-Schrieffer-Heeger model: Polaron excitations and optical absorption [O] . Harigaya, Kikuo 1992

机译：掺杂C_ {60}和C_ {60}中的晶格畸变和能级结构 C_ {70}研究了扩展的su-schrieffer-Heeger模型：polaron 激发和光学吸收

Photloinduced Electron Transfer and Adduct Formation between C_(60)/C_(70) and Optically Active 1,1'-Binaphthyl-2,2'-diamine

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