Kinetics of Photoresponse of the Chlorine Dioxide-Iodine-Malonic Acid Reaction

Attila K. Horvath; Milos Dolnik; Anatol M. Zhabotinsky; Irving R. Epstein

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Kinetics of Photoresponse of the Chlorine Dioxide-Iodine-Malonic Acid Reaction

机译：二氧化氯-碘-丙二酸反应的光响应动力学

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We studied the photoresponse of the chlorine dioxide-iodine-malonic acid (CDIMA) reaction. In a continuously fed stirred tank reactor, the photosensitivity increases with decreasing residence time and increasing concentration of chlorine dioxide. Under certain conditions, concentrations change in a sigmoidal fashion in response to a jump in the intensity of illumination. We propose a new mechanism for the effect of visible light on the CDIMA reaction. Simulations based on the proposed mechanism accurately describe the experimentally observed kinetics.

机译：我们研究了二氧化氯-碘-丙二酸（CDIMA）反应的光响应。在连续进料的搅拌釜反应器中，光敏度随着停留时间的减少和二氧化氯浓度的增加而增加。在某些条件下，浓度会根据照明强度的变化以S形变化。我们为可见光对CDIMA反应的影响提出了一种新的机制。基于提出的机制的仿真准确地描述了实验观察到的动力学。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2000年第24期|共4页
作者
Attila K. Horvath; Milos Dolnik; Anatol M. Zhabotinsky; Irving R. Epstein;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Kinetics of Photoresponse of the Chlorine Dioxide-Iodine-Malonic Acid Reaction [J] . Attila K. Horvath, Milos Dolnik, Anatol M. Zhabotinsky, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2000,第24期

机译：二氧化氯-碘-丙二酸反应的光响应动力学
2. Stability, Bifurcation Analysis and Chaos Control in Chlorine Dioxide-Iodine-Malonic Acid Reaction [J] . Din Qamar, Donchev Tzanko, Kolev Dimitar Match . 2018,第3期

机译：二氧化碘 - 碘丙酸反应中稳定性，分岔分析和混沌控制
3. Target Turing Patterns and Growth Dynamics in the Chlorine Dioxide-Iodine-Malonic Acid Reaction [J] . Asher Preska Steinberg, Irving R. Epstein, Milos Dolnik The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2014,第13期

机译：二氧化氯-碘-丙二酸反应中的目标图灵模式和生长动力学
4. Kinetics of the Reaction for Generation of Chlorine Dioxide from Sodium Chlorate and Hydrochloric Acid [C] . Xinjie Li, Dandan Jiang, Yuejun Zhang ICCMME 2012 . 2013

机译：用氯酸钠和盐酸产生二氧化氯的反应动力学
5. Turing pattern formation in the chlorine dioxide-iodine-malonic acid reaction-diffusion system. [D] . Setayeshgar, Sima. 1998

机译：在二氧化氯-碘-丙二酸反应-扩散系统中形成图灵模式。
6. Theoretical study of the kinetics of reactions of the monohalogenated methanes with atomic chlorine [O] . Katarzyna Brudnik, Maria Twarda, Dariusz Sarzyński, -1

机译：单卤甲烷与原子氯反应动力学的理论研究
7. Turing patterns in the chlorine dioxide-iodine-malonic acid reaction with square spatial periodic forcing [O] . Feldman Daniel, Nagao Raphael, Bansagi Tamas Jr., 2012

机译：平方空间周期性强迫的二氧化氯-碘-丙二酸反应中的图灵模式
8. Reactions of Chlorine Dioxide and Other Oxy-Chloro Compounds with Organic Compounds. Kinetics and Mechanisms of the Reaction Between Chlorite and Hypochlorous Acid in Aqueous Solution [R] . Granstrom, M. L., Israel, B. M., Snow, W. B., 1964

机译：二氧化氯和其他氧氯化合物与有机化合物的反应。亚氯酸盐与次氯酸在水溶液中反应的动力学和机理

Kinetics of Photoresponse of the Chlorine Dioxide-Iodine-Malonic Acid Reaction

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