Reactions of Laser-Ablated Mo and W Atoms with Dinitrogen: Infrared Spectra of Metal Nitrides, Dinitrides, and Complexes in Solid Argon and Nitrogen

Lester Andrews; Philip F. Souter; William D. Bare; Binyong Liang

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Reactions of Laser-Ablated Mo and W Atoms with Dinitrogen: Infrared Spectra of Metal Nitrides, Dinitrides, and Complexes in Solid Argon and Nitrogen

机译：激光烧蚀的Mo和W原子与氮的反应：固体氩气和氮气中金属氮化物，二氮化物和配合物的红外光谱

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Laser-ablated Mo and W atoms react with N_2 in excess nitrogen and argon to form the metal nitrides, MN, and ligated complexes, (NN)_xMN, the metal dinitrides, NMN, and ligated complexes, (NN)_xMN_2, and several complexes M(NN)_x leading up to the octahedral species with x = 6. On the basis of the resolution of natural abundance Mo isotopes and ~(15)N substitution, the open, bent NMoN molecule valence angle is 106 +- 3 deg. The dinitride molecules are formed both by direct insertion of metastable metal atoms into dinitrogen and by the addition of atomic nitrogen to the mononitride molecule.

机译：激光烧蚀的Mo和W原子与过量的氮和氩中的N_2反应形成金属氮化物，MN和连接的配合物（NN）_xMN，金属二氮化物NMN和连接的配合物（NN）_xMN_2和几种配合物M（NN）_x导致x = 6的八面体物种。根据自然丰度Mo同位素的分辨率和〜（15）N取代，开放的弯曲NMoN分子化合价角为106±3度。通过将亚稳定的金属原子直接插入二氮中以及通过向单氮化物分子中添加原子氮来形成二氮化物分子。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1999年第24期|共10页
作者
Lester Andrews; Philip F. Souter; William D. Bare; Binyong Liang;
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中图分类物理化学（理论化学）、化学物理学;
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Reactions of Laser-Ablated Mo and W Atoms with Dinitrogen: Infrared Spectra of Metal Nitrides, Dinitrides, and Complexes in Solid Argon and Nitrogen

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