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首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >An ordered mesoporous aluminosilicate oxynitride template to prepare N-incorporated ordered mesoporous carbon
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An ordered mesoporous aluminosilicate oxynitride template to prepare N-incorporated ordered mesoporous carbon

机译：有序介孔铝硅氧氮氧化物模板，用于制备掺入N的有序介孔碳

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摘要

The synthesis and characterization of amorphous N-incorporated carbon materials, with ordered mesoporous structure, using mesoporous aluminosilicate oxynitride (OMASON) as a solid template for the first time is reported. The use of furfuryl alcohol (FA) as carbon precursor generates the N-incorporated mesoporous carbon material with nitrogen contents of similar to 1.4-3.1 wt %. The nitrogen-containing groups existing in the OMASON template participate in the reactions during the carbonization process of polymerized FA/template composite, resulting in the formation of nitrogen-containing groups in the resulting mesoporous N-incorporated carbon materials. The nitrogen contents of the obtainable mesoporous carbon materials evidently decrease with increasing carbonization temperatures from 700 to 900 degrees C. Oppositely, the textural properties of mesoporous N-incorporated carbon materials are almost independent of the carbonization temperatures. All N-incorporated mesoporous carbon material have a high specific surface area (similar to 1600 m(2)/g) and high mesopore volume (similar to 1.6 cm(3)/g) and a uniform mesopore size distribution. And the morphologies of the N-incorporated mesoporous carbon materials also derive from that of the OMASON template.
机译：首次报道了以介孔铝硅氧氮氧化物（OMASON）为固体模板的，有序介孔结构的非晶态N结合碳材料的合成与表征。使用糠醇（FA）作为碳前体会产生氮含量接近1.4-3.1 wt％的N结合介孔碳材料。 OMASON模板中存在的含氮基团在聚合的FA /模板复合材料的碳化过程中参与反应，导致在所得的中孔掺氮碳材料中形成含氮基团。随着碳化温度从700℃升高到900℃，可获得的介孔碳材料的氮含量明显降低。相反，结合了N的介孔碳材料的组织性质几乎与碳化温度无关。所有掺入N的中孔碳材料均具有较高的比表面积（类似于1600 m（2）/ g）和较高的中孔体积（类似于1.6 cm（3）/ g）和均匀的中孔尺寸分布。掺氮的介孔碳材料的形态也源自OMASON模板的形态。

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