ONE AND TWO ROUTE PROCESSES OF ACETONE AND ACETONITRILE BONDING FROM THE GAS PHASE WITH POLYOXOMETALLATES OF TETRAAMINE COMPLEXES OF NICKEL(II) AND COPPER(II)

A. V. Barna; Ya. D. Lampeka

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ONE AND TWO ROUTE PROCESSES OF ACETONE AND ACETONITRILE BONDING FROM THE GAS PHASE WITH POLYOXOMETALLATES OF TETRAAMINE COMPLEXES OF NICKEL(II) AND COPPER(II)

机译：气相与镍（II）和铜（II）的四胺配合物的聚甲醛金属缩合物的丙酮和乙腈键合的一两个路线过程

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It has been established that the rate of bonding of acetone or acetonitrile molecules to compounds formed from ammine complexes of copper(II) and nickel(II) with polyoxometallates, is described by one of two parallel processes. Drawing on previous data for reactions with other polar molecules, it was shown that the mechanism of interaction did not depend on the chemical nature of the adsorbale, and on this basis it was proposed that the differences in adsorption is associated with differences in the crystal structure of the adsorbents.

机译：已经确定，丙酮或乙腈分子与由铜（II）和镍（II）的胺配合物与多金属氧酸盐形成的化合物的键合速率是通过两种并行方法之一描述的。根据先前与其他极性分子反应的数据，表明相互作用的机理不取决于吸附剂的化学性质，并在此基础上提出吸附的差异与晶体结构的差异有关的吸附剂。

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《Theoretical and Experimental Chemistry》 |2010年第1期|共6页
作者
A. V. Barna; Ya. D. Lampeka;
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正文语种 eng
中图分类化学;
关键词
copper(II); nickel(II); amine complexes; polyoxometallates; kinetics of adsorption; polar molecules;

机译：铜（II）;镍（II）;胺络合物;多金属氧酸盐;吸附动力学;极性分子;

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1. ONE AND TWO ROUTE PROCESSES OF ACETONE AND ACETONITRILE BONDING FROM THE GAS PHASE WITH POLYOXOMETALLATES OF TETRAAMINE COMPLEXES OF NICKEL(II) AND COPPER(II) [J] . A. V. Barna, Ya. D. Lampeka Theoretical and Experimental Chemistry . 2010,第1期

机译：气相与镍（II）和铜（II）的四胺配合物的聚甲醛金属缩合物的丙酮和乙腈键合的一两个路线过程
2. The interaction of nickel(II) and copper(II) schiff base complexes with diorganotin(IV) dichlorides in acetonitrile: A thermodynamic study [J] . Asadi Z., Asadi M., Mosalanezhad F. Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2011,第8a10期

机译：镍（II）和铜（II）席夫碱络合物与二氯化二有机锡（IV）在乙腈中的相互作用：热力学研究
3. Hydrogen Bonds as Structural Directive towards Unusual Polynuclear Complexes: Synthesis, Structure, and Magnetic Properties of Copper(II) and Nickel(II) Complexes with a 2-Aminoglucose Ligand [J] . Burkhardt A, Spielberg ET, Simon S, Chemistry: A European journal . 2009,第5期

机译：氢键作为对不寻常的多核配合物的结构指导：具有2-氨基葡萄糖配体的铜（II）和镍（II）配合物的合成，结构和磁性
4. Highly polarizable metallic complexes for nonlinear optics copper(II) andnickel(II) complexes of bis(salicylaldiminato) Schiff base, [C] . Abdalla M. Darwish, Alabama AM Univ., Huntsville, Nonlinear Optical Properties of Organic Materials IX . 1996

机译：高极化金属配合物，用于双（水杨基铝亚胺）Schiff碱的非线性光学铜（II）和镍（II）配合物，
5. Investigation of copper(II) complexes: I. Copper(II) complexes of tryptophan and its analogues as postcolumn interaction components for indirect fluorescence detection of amino-containing analytes. II. High-performance liquid chromatographic separation of copper(II) azamacrocyclic complexes. [D] . Shen, Xiaoxuan. 2006

机译：铜（II）配合物的研究：I.色氨酸及其类似物作为柱后相互作用组分的铜（II）配合物，用于间接荧光检测含氨基的分析物。二。铜（II）氮杂大环配合物的高效液相色谱分离。
6. Synthesis and Spectral Investigations of Manganese(II) Cobalt(II) Nickel(II) Copper(II) and Zinc(II) Complexes of New Polydentate Ligands Containing a 18-Naphthyridine Moiety [O] . Sreedasyam Jagannatha Swamy, Erra Ram Reddy, Devunuri Naga Raju, 2006

机译：新型含18-萘啶基多齿配体的锰（II）钴（II）镍（II）铜（II）和锌（II）配合物的合成和光谱研究
7. A structural investigation of the hydrogen bonding in copper (II), nickel (II), and palladium (II) complexes of some vic-dioximes [O] . Bowers, Raymond Harold 1971

机译：某些二恶英在铜（II），镍（II）和钯（II）配合物中氢键的结构研究
8. Dimethyl Sulfoxide Complexes of Chromium(Iii), Manganese(Ii), Iron(Iii), Nickel(Ii), and Copper(Ii) Nitrates and Magnesium and Nickel(Ii) Perchlorates. Part 1. Preparation and Nuclear Magnetic Resonance and Infrared Studies [R] . Moniz, W. B., Poranski, C. F., Venezky, D. L. 1967

机译：二甲基亚砜配合物的铬（III），锰（Ii），铁（Iii），镍（Ii）和铜（Ii）硝酸盐和镁和镍（Ii）高氯酸盐。第1部分。制备和核磁共振和红外研究

ONE AND TWO ROUTE PROCESSES OF ACETONE AND ACETONITRILE BONDING FROM THE GAS PHASE WITH POLYOXOMETALLATES OF TETRAAMINE COMPLEXES OF NICKEL(II) AND COPPER(II)

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