EFFECT OF THE TYPE OF CRYSTAL LATTICE IN NICKEL(II) AND COPPER(II) MACROCYCLIC CARBOXYLATES ON ABSORPTION OF COPPER AMINE COMPLEXES FROM SOLUTIONS

I. L. Andriichuk; L. V. Tsymbal; Ya. D. Lampeka

首页> 外文期刊>Theoretical and Experimental Chemistry >EFFECT OF THE TYPE OF CRYSTAL LATTICE IN NICKEL(II) AND COPPER(II) MACROCYCLIC CARBOXYLATES ON ABSORPTION OF COPPER AMINE COMPLEXES FROM SOLUTIONS

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EFFECT OF THE TYPE OF CRYSTAL LATTICE IN NICKEL(II) AND COPPER(II) MACROCYCLIC CARBOXYLATES ON ABSORPTION OF COPPER AMINE COMPLEXES FROM SOLUTIONS

机译：镍（II）和铜（II）宏观羧酸盐中的晶格类型对溶液中铜胺络合物吸收的影响

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We have established that crystalline nickel-containing metal-organic frameworks (MOFs) bind the complex [Cu(NH3)4](ClO4)2 from acetonitrile solutions and do not react with [Cu(en)](ClO4)2. The MOF/copper ammine complex ratio in the products after reaching saturation is determined by the crystal lattice structures of the compounds, and increases from 1.2 (one-dimensional coordination polymer, 1D CP) to 3.2 (2D CP) and 3.9 (ionic MOF) moles of copper ammine complex per formula unit of sorbent. We have shown that it is possible to convert the bound ammine complex to nanosized copper(II) sulfide by treatment with sodium sulfide.

机译：我们已经确定，结晶的含镍金属有机骨架（MOF）结合乙腈溶液中的复合物[Cu（NH3）4]（ClO4）2，并且不与[Cu（en）]（ClO4）2反应。达到饱和后，产物中的MOF /铜氨配合物比率由化合物的晶格结构决定，从1.2（一维配位聚合物，1D CP）增加到3.2（2D CP）和3.9（离子MOF）。分子式每吸附剂单位摩尔摩尔数的铜氨配合物。我们已经表明可以通过用硫化钠处理将结合的胺配合物转化为纳米尺寸的硫化铜（II）。

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《Theoretical and Experimental Chemistry》 |2010年第1期|共6页
作者
I. L. Andriichuk; L. V. Tsymbal; Ya. D. Lampeka;
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正文语种 eng
中图分类化学;
关键词
azamacrocyclic complexes; nickel; carboxylates; nanoparticles; copper(II) ammine complex; copper(II) sulfide;

机译：氮杂大环配合物;镍;羧酸盐;纳米颗粒;铜（II）胺配合物;硫化铜（II）;

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1. 乙二胺改性木屑黄原酸盐对水溶液中Cu（II）和Ni（II）离子吸附平衡及动力学 [J] . 夏璐, 胡伊旭, 张博涵中国有色金属学报（英文版） . 2014,第003期
2. EFFECT OF THE TYPE OF CRYSTAL LATTICE IN NICKEL(II) AND COPPER(II) MACROCYCLIC CARBOXYLATES ON ABSORPTION OF COPPER AMINE COMPLEXES FROM SOLUTIONS [J] . I. L. Andriichuk, L. V. Tsymbal, Ya. D. Lampeka Theoretical and Experimental Chemistry . 2010,第1期

机译：镍（II）和铜（II）宏观羧酸盐中的晶格类型对溶液中铜胺络合物吸收的影响
3. Synthesis and properties of a tetraaza macrocyclic ligand containing 2-pyridylmethyl pendant arms and its copper(II) and nickel(II) complexes: crystal structure of the copper(II) complex [J] . Kang SG., Jeong JH., Kim SJ. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第18期

机译：含2-吡啶基甲基侧链的四氮杂大环配体及其铜（II）和镍（II）配合物的合成与性能：铜（II）配合物的晶体结构
4. MAGNETIC PROPERTIES OF BINUCLEAR MANGANESE(II), COBALT(II), NICKEL(II) AND COPPER(II) COMPLEXES OF A MACROCYCLIC LIGAND DERIVED FROM PYRIDINE-N-OXIDE, AND CRYSTAL STRUCTURE OF THE NICKEL COMPLEX [J] . Blake AB., Yavari A., Moubaraki B., Inorganica Chimica Acta . 1995,第1a2期

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5. Nanoscale Permanent rings in Two- or Three-Dimensional Structure Constructed by the Self-Assembly of Copper(II)-Macrocyclic Complexes and Tetracyanonickelate(II) [C] . Chee-Hun Kwak, Mee Chang, Minchul Chung International Conference onaterials Science and Chemical Engineering . 2013

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6. I. THE SYNTHESES, SOLUTION BEHAVIOR, CRYSTAL STRUCTURES AND MAGNETIC PROPERTIES OF SOME IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES. II. THE CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A TRICOPPER(II) CLUSTER CONTAINING A TRIPLY BRIDGING CARBONATE GROUP. [D] . KOLKS, GARY ARNOLD. 1980

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8. Copper complexes with new oxaaza-pendant-armed macrocyclic ligands: X-ray crystal structure of a macrocyclic copper(II) complex [O] . Vicente Manuel, Bastida Rufina, Macías Alejandro, 2005

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9. CRYSTAL STRUCTURES OF NICKEL AND COPPER COMPOUNDS PART I. TWO BIS COMPLEXES OF 2.2’-IMINOBIS (ACETAMIDOXIME) PART II REGULAR OCTAHEDRAL COPPER (II) COMPLEXES [R] . DAVID LAWRENCE CULLEN 1969

机译：镍和铜化合物的晶体结构第一部分2.2'-亚氨基（乙酰氨基）第二部分正二甲基铜（Ⅱ）配合物的两个双配合物

EFFECT OF THE TYPE OF CRYSTAL LATTICE IN NICKEL(II) AND COPPER(II) MACROCYCLIC CARBOXYLATES ON ABSORPTION OF COPPER AMINE COMPLEXES FROM SOLUTIONS

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