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首页> 外文期刊>Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems >THE ENTHALPIES OF SOLUTION OF 2-CHLORO-2-METHYLPROPANE, 2-CHLORO-2-METHYLBUTANE AND 3-CHLORO-3-METHYLPENTANE IN MONO- AND DIALCOHOLS AT 298.15 K
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THE ENTHALPIES OF SOLUTION OF 2-CHLORO-2-METHYLPROPANE, 2-CHLORO-2-METHYLBUTANE AND 3-CHLORO-3-METHYLPENTANE IN MONO- AND DIALCOHOLS AT 298.15 K

机译:在298.15 K下单和二元醇中2-氯-2-甲基丙烷,2-氯-2-甲基丁烷和3-氯-3-甲基戊烷的溶解焓

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摘要

The enthalpies of solution at infinite dilution of 2-chloro-2-methylpropane in 9 dialcohols and of 2-chloro-2-methylbutane and 3-chloro-3-methylpentane in 19 mono- and dialcohols, at 298.15 K, were measured using a solution calorimeter. These values are discussed in terms of solute-solvent interactions. Together with previous data, this information provides a thermodynamic picture of the effect of the size of the alkyl chlorides and the structure of the alcohols. [References: 14]
机译:在298.15 K下,使用298.15 K测量了在9种二醇中无限稀释2-氯-2-甲基丙烷和在19种一元醇和二醇中的2-氯-2-甲基丁烷和3-氯-3-甲基戊烷的溶液焓。溶液量热仪。这些值是根据溶质与溶剂的相互作用进行讨论的。与先前的数据一起,该信息提供了烷基氯的大小和醇的结构的影响的热力学图。 [参考:14]

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