Asymmetric Modular Synthesis of Cylindrically Chiral FerroPHOS Ligands for the Rh-Catalyzed Asymmetric Hydroboration

Jahyo Kang; Jun Hee Lee; Jin Bum Kim; Gi Jeong Kim

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Asymmetric Modular Synthesis of Cylindrically Chiral FerroPHOS Ligands for the Rh-Catalyzed Asymmetric Hydroboration

机译：Rh催化不对称硼氢化反应的柱状手性FerroPHOS配体的不对称模块化合成

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摘要

Asymmetric modular synthesis of air-stable ferrocenyl bisphosphine ligands with cylindrical chirality was achieved employing asymmetric catalytic methods and these chiral ligands were screened in asymmetric hydroboration reaction.

机译：采用不对称催化方法实现了具有圆柱形手性的空气稳定的二茂铁基双膦配体的不对称模块化合成，并在不对称硼氢化反应中筛选了这些手性配体。

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《Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry》 |2000年第6期|共5页
作者
Jahyo Kang; Jun Hee Lee; Jin Bum Kim; Gi Jeong Kim;
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正文语种 eng
中图分类分子生物学;
关键词
asymmetric catalysis; chirality; hydroborations P ligands; rhodium;

机译：不对称催化;手性;硼氢化硼配体;铑;

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专利

1. Asymmetric Modular Synthesis of Cylindrically Chiral FerroPHOS Ligands for the Rh-Catalyzed Asymmetric Hydroboration [J] . Jahyo Kang, Jun Hee Lee, Jin Bum Kim, Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2000,第5a6期

机译：Rh催化不对称硼氢化反应的柱状手性FerroPHOS配体的不对称模块化合成
2. Asymmetric synthesis of chiral Roche ester and its derivatives via Rh-catalyzed enantioselective hydrogenation with chiral phosphine-phosphoramidite ligands [J] . Qiu Min, Wang Dao-Yong, Hu Xiang-Ping, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2009,第2期

机译：手性膦-亚磷酰胺配体经Rh催化对映选择性加氢不对称合成手性罗氏酯及其衍生物
3. Carbohydrate phosphinites as practical ligands in symmetric catalysis: electronic effects and dependence of backbone chirality in rh-catalyzed asymmetric hydrogenations. Synthesis of R- or s-amino acids using natural sugars as ligand precursors [J] . T.V.RajanBabu, Timothy A.Ayers, Gary A.Halliday The Journal of Organic Chemistry . 1997,第17期

机译：碳水化合物次膦酸盐作为对称催化中的实用配体：rh催化不对称氢化中的电子效应和主链手性的依赖性。使用天然糖作为配体前体合成R-或s-氨基酸
4. SYNTHESIS OF CHIRAL LIGAND WITH PERFLUOROALKYL GROUPS FOR HIGHLY EFFECTIVE ASYMMETRIC SYNTHESIS [C] . Y. S. Sokeirik, Atsushi Tarui, Kazuyuki Sato, Treatise Gist Anthology . 2007

机译：高效全不对称合成具有全氟烷基的手性配体
5. Development of new chiral chelating ferrocenyl ligands for transition metal catalyzed asymmetric carbon -carbon bond formations: A modular approach for ligand design and synthesis [D] . Cheung, Hong Yee 2008

机译：用于过渡金属催化的不对称碳-碳键形成的新手性螯合二茂铁基配体的开发：配体设计和合成的模块化方法
6. Asymmetric synthesis of γ-chiral borylalkanes via sequential reduction/hydroboration using a single copper catalyst [O] . Jung Tae Han, Jin Yong Lee, Jaesook Yun 2020

机译：通过使用单铜催化剂通过顺序减少/氢化的γ-手性硼烷烃的不对称合成
7. Chiral bidentate phosphabenzene-based ligands: synthesis, coordination chemistry, and application in Rh-catalyzed asymmetric hydrogenations [O] . Müller, C Christian, Guarrotxena Lopez, L, Kooijman, H, 2006

机译：手性双齿膦基苯配体：合成，配位化学及其在Rh催化不对称氢化中的应用

Asymmetric Modular Synthesis of Cylindrically Chiral FerroPHOS Ligands for the Rh-Catalyzed Asymmetric Hydroboration

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