First Diastereoselective Passerini-Smiles and Ugi-Smiles Reactions Using Chiral Aldehydes

Palakodety Radha Krishna; Gandrath Dayaker; D. Venkata Ramana; Ramesh Kunde

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First Diastereoselective Passerini-Smiles and Ugi-Smiles Reactions Using Chiral Aldehydes

机译：使用手性醛的第一个非对映选择性Passerini-Smiles和Ugi-Smiles反应

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摘要

A diastereoselective O/N-arylative Passerini/Ugi reaction of chiral aldehydes with commercially available isocyanides affordingO-aryl amides and N-aryl amides, respectively, as products in moderate to good yields, together with de values, is reported.

机译：据报道，手性醛与可商购获得的异氰酸酯的非对映选择性的O / N-芳基Passerini / Ugi反应，分别提供O-芳基酰胺和N-芳基酰胺，作为中等至良好产率的产物，以及de值。

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《Helvetica chimica acta》 |2014年第8期|共12页
作者
Palakodety Radha Krishna; Gandrath Dayaker; D. Venkata Ramana; Ramesh Kunde;
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正文语种 eng
中图分类化学;
关键词
First Diastereoselective; Passerini-Smiles; Ugi-Smiles;

机译：首次非对映选择性;Passerini-Smiles;Ugi-Smiles;

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1. First Diastereoselective Passerini-Smiles and Ugi-Smiles Reactions Using Chiral Aldehydes [J] . Palakodety Radha Krishna, Gandrath Dayaker, D. Venkata Ramana, Helvetica chimica acta . 2014,第8期

机译：使用手性醛的第一个非对映选择性Passerini-Smiles和Ugi-Smiles反应
2. Enantio- and diastereoselective hetero-Diels-Alder reactions between 4-methyl-substituted Rawal's diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates: catalytic asymmetric synthesis of (-)-cis-aerangis lactone [J] . Yudai Watanabe, Naoyuki Shimada, Masahiro Anada, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2014,第1期

机译：手性氨基甲酸二（II）羧酸酯催化4-甲基取代的拉瓦尔二烯与醛之间的对映和非对映选择性杂Diels-Alder反应：（-）-顺式-aerangis内酯的催化不对称合成
3. Enantio- and diastereoselective hetero-Diels-Alder reactions between 2-aza-3-silyloxy-1,3-butadienes and aldehydes catalyzed by chiral dirhodium(n) carboxamidates [J] . Yudai Watanabe, Takuya Washio, Janagiraman Krishnamurthi, Chemical Communications . 2012,第55期

机译：手性氨基甲酸酯（n）催化2-氮杂-3-甲硅烷氧基-1,3-丁二烯与醛之间的对映和非对映选择性杂Diels-Alder反应
4. Double Stereodifferentiating Studies in Boron-Mediated Aldol Reactions of Chiral Methyl Ketones and Chiral Aldehydes [C] . Savio Moita Pinheiro, Andrea Maria Aguilar, Luiz Carlos Dias European Symposium on Organic Chemistry . 2009

机译：硼介导的手性甲基酮和手性醛反应的双立体二氧化性研究
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Synthesis of Polyoxygenated Heterocycles by Diastereoselective Functionalization of a Bio-Based Chiral Aldehyde Exploiting the Passerini Reaction [O] . Gabriella Vitali Forconesi, Luca Banfi, Andrea Basso, 2020

机译：基于生物基手性醛的非对映选择性官能化的聚氧化杂环的合成探索Passerini反应的基于生物的手性醛官能化
7. Correction to “Diastereoselective Passerini Reaction of Biobased Chiral Aldehydes: Divergent Synthesis of Various Polyfunctionalized Heterocycles” [O] . Lisa Moni, Luca Banfi, Andrea Basso, 2016

机译：校正“生物化手性醛的非对映选择性偏移偏移：各种多官能化杂环的发散合成”
8. Chiral Synthesis via Organoboranes. 33. The Controlled Reaction of B-Alkydiisopinocampheylboranes with Aldehydes Providing a Convenient Procedure for the Enantiomeric Enrichment of the Boronic Ester Products Through Kinetic Resolution [R] . Joshi, N. N., Pyun, C., Mahindroo, V. K., 1991

机译：有机硼烷的手性合成。 33.B-烷基异哌啶基硼烷与醛的可控反应通过动力学拆分提供了对硼酸酯产物对映体富集的方便程序

First Diastereoselective Passerini-Smiles and Ugi-Smiles Reactions Using Chiral Aldehydes

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