Synthesis, Crystal Structure, and Characterization of Two Novel Five-coordinate Zinc(II) Complexes with the Tripod Ligand Tris(N-methylbenzimidazol-2-yl-methyl)amine and alpha,beta-unsaturated Carboxylates

Wu HL; Sun T; Li K; Xu YH; Yun RR; Sun QY

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Synthesis, Crystal Structure, and Characterization of Two Novel Five-coordinate Zinc(II) Complexes with the Tripod Ligand Tris(N-methylbenzimidazol-2-yl-methyl)amine and alpha,beta-unsaturated Carboxylates

机译：三脚架配体三（N-甲基苯并咪唑-2-基甲基）胺和α，β-不饱和羧酸盐的两种新型五配位锌（II）配合物的合成，晶体结构和表征

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Two novel Five-coordinate zinc(H) complexes with the tripod ligand tris(N-methylbenzimidazol-2-ylmethyl)amine (Mentb) and two different alpha,beta-unsaturated carboxylates, with the composition [Zn(Mentb)(acrylate)] (ClO4)center dot DMF center dot 1.5CH(3)OH (1) and [Zn(Mentb)(cinnamate)](ClO4)center dot 2DMF center dot 0.5CH(3)OH (2), were synthesized and characterized by means of elemental analyses, electrical conductivity measurements, IR, UV. and H-1 NMR spectra. The crystal structure of two complexes have been determined by a single-crystal X-ray diffraction method. and show that the Zn-II atom is bonded to a Mentb ligand and a alpha,beta-unsaturated carboxylate Molecule through four N atoms and one 0 atom, resulting in a distorted trigonal-bipyramidal coordination [tau(1) = 0.853. tau(2) = 0.8551, with approximate C-3 symmetry.

机译：两个新的五配位锌（H）与三脚架配体三（N-甲基苯并咪唑-2-基甲基）胺（Mentb）和两个不同的α，β-不饱和羧酸盐的配合物，其组成为[Zn（Mentb）（丙烯酸酯）]合成并表征了（ClO4）中心点DMF中心点1.5CH（3）OH（1）和[Zn（Mentb）（肉桂酸酯）]（ClO4）中心点2DMF中心点0.5CH（3）OH（2）元素分析的手段，电导率测量，IR，UV。和H-1 NMR光谱。两种配合物的晶体结构已经通过单晶X射线衍射法确定。并表明Zn-II原子通过四个N原子和一个0原子与Mentb配体和一个α，β-不饱和羧酸分子键合，导致扭曲的三角-双锥体配位[tau（1）= 0.853。 tau（2）= 0.8551，具有近似C-3对称性。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第1期|共5页
作者
Wu HL; Sun T; Li K; Xu YH; Yun RR; Sun QY;
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正文语种 eng
中图分类化学;
关键词
Zinc; Tripod ligands; Crystal structures; MOLECULAR-STRUCTURE; COPPER(II) COMPLEX; TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE; MANGANESE(II); NICKEL(II); AMINE;

机译：锌;三脚架配体;晶体结构;分子结构;铜（II）络合物;三（2-苯并咪唑基甲基）胺;锰（II）;镍（II）;胺;

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1. Synthesis, Crystal Structure, and Characterization of Two Novel Five-coordinate Zinc(II) Complexes with the Tripod Ligand Tris(N-methylbenzimidazol-2-yl-methyl)amine and alpha,beta-unsaturated Carboxylates [J] . Wu HL, Sun T, Li K, Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第1期

机译：三脚架配体三（N-甲基苯并咪唑-2-基甲基）胺和α，β-不饱和羧酸盐的两种新型五配位锌（II）配合物的合成，晶体结构和表征
2. Synthesis,crystal structure and characterization of zinc(II)complexes with the tripod ligand tris(2-benzimidazolylmethyl)amine and alpha,beta-unsaturated carboxylates [J] . Hui-lu Wu, Yi-ci Gao, Kai-bei Yu Transition Metal Chemistry . 2004,第2期

机译：三脚架配体三（2-苯并咪唑基甲基）胺和α，β-不饱和羧酸盐的锌（II）配合物的合成，晶体结构和表征
3. Synthesis, crystal structure and properties of manganese(II) complexes with the tripod ligand tris(2-benzimidazylmethyl)amine and alpha,beta-unsaturated carboxylates [J] . HUI-LU WU, YI-CI GAO Journal of Coordination Chemistry . 2006,第2期

机译：三脚架配体三（2-苯并咪唑基甲基）胺和α，β-不饱和羧酸盐锰（II）配合物的合成，晶体结构和性能
4. Synthesis, characterization and emission properties of yttrium(III), europium(III), and terbium(III) complexes of tris(2-(2-hydroxy-3- trifluoromethoxylbenzylideneamino)ethyl)amine [C] . Masatoshi Kanesato, Yoshihiro Kikkawa, Midori Goto Rare Earth Research Conference . 2011

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5. Synthesis, Structure and Photochemistry of Fe(III) Complexes with Tripodal Amine Chelates Containing alpha-hydroxy Acid and alpha-hydroxy Amide Groups. [D] . Vernia, Jennifer E. 2017

机译：Fe（III）与含有α-羟基酸和α-羟基酰胺基团的三脚架胺螯合物的合成，结构和光化学。
6. Synthesis crystal structure and investigation of mononuclear copper(II) and zinc(II) complexes of a new carboxylate rich tripodal ligand and their interaction with carbohydrates in alkaline aqueous solution [O] . Christopher D. Stewart, Mayra Pedraza, Hadi Arman, -1

机译：一种新的富含羧酸盐的三脚架配体的单核铜（II）和锌（II）配合物的合成晶体结构及其在碱性水溶液中与碳水化合物的相互作用的研究
7. Template synthesis, crystal structure and luminescent properties of neutral N4O3 tripodal LnIIIL complexes (Ln III = La3+, Eu3+, Gd3+, Tb 3+, Dy3+, Ho3+, Er3+, Tm3+ or Lu3+; H3L = Tris{3′-(2″- pyridyl)-5′-tert-butyl-2′-hydroxybenzylidene-2-iminoethyl}amine) [O] . Wong WK, Liang H, Guo J, 2004

机译：中性N4O3三脚架LnIIIL配合物（Ln III = La3 +，Eu3 +，Gd3 +，Tb 3 +，Dy3 +，Ho3 +，Er3 +，Tm3 +或Lu3 +的模板合成，晶体结构和发光特性; H3L = Tris {3'-（2''-吡啶基）-5'-叔丁基-2'-羟基亚苄基-2-亚氨基乙基}胺）

Synthesis, Crystal Structure, and Characterization of Two Novel Five-coordinate Zinc(II) Complexes with the Tripod Ligand Tris(N-methylbenzimidazol-2-yl-methyl)amine and alpha,beta-unsaturated Carboxylates

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