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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Aspects of the Coordination Chemistry of 1,1 '-Bis(benzothiazol-2-ylthio)ferrocene
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Aspects of the Coordination Chemistry of 1,1 '-Bis(benzothiazol-2-ylthio)ferrocene

机译:1,1'-双(苯并噻唑-2-基硫基)二茂铁的配位化学方面

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摘要

1,1'-Bis(benzothiazol-2-ylthio)ferrocene (1) acts as a bridging bidentate N,N-ligand and affords coordination polymers with a range of Cu-I, Ag-I, Cu-II, Zn-II and Hg-II salts. The crystal structures of [Ag(CF3SO3)(mu-1)](n), [CuCl2(mu-1)]n, [ZnCl2(mu-1)](n) and [HgBr2(mu-1)](n) have been determined. The silver atom exhibits a weak contact to a cyclopentadienyl pi-system in addition to its trigonal-planar coordination. The copper atom is in a square-planar coordination environment, whereas the coordination of zinc and mercury is best described as distorted tetrahedral in the corresponding complexes.
机译:1,1'-双(苯并噻唑-2-基硫基)二茂铁(1)充当桥联双齿N,N-配体,并提供具有一系列Cu-I,Ag-I,Cu-II,Zn-II的配位聚合物和Hg-II盐。 [Ag(CF3SO3)(mu-1)](n),[CuCl2(mu-1)] n,[ZnCl2(mu-1)](n)和[HgBr2(mu-1)]( n)已经确定。除了其三角平面配位之外,银原子还表现出与环戊二烯基pi系统的弱接触。铜原子处于方形平面配位环境中,而锌和汞的配位最好描述为相应配合物中的扭曲四面体。

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