Syntheses, structures, and fluorescence of two novel 2D zinc(II) layered frameworks based on 3-amino-1, 2, 4-triazole

Gao J.-Y.; Xiong X.-H.; Chen C.-J.; Xie W.-P.; Ran X.-R.; Yue S.-T.

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Syntheses, structures, and fluorescence of two novel 2D zinc(II) layered frameworks based on 3-amino-1, 2, 4-triazole

机译：基于3-amino-1，2，4-triazole的两种新型2D锌（II）层状骨架的合成，结构和荧光

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Two 2D zinc(II) layered coordination polymer compounds [Zn_ 2(atz)_2(na)_2]_n (1), and [Zn(atz)(ina)]_n (2) (Hatz = 3-amino-1H-1, 2, 4-triazole, na = nicotinic acid, ina = isonicotinic acid) were synthesized and structurally characterized by elemental analysis, FT-IR, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction. The interconnection of a coplanar six-membered hexagonal ring and a 16-membered non-planar chair-like ring results in a 2D sheet with (4, 8~2) topological network. Hydrogen bonds connect the neighboring planes into 3D supramolecular architectures. Furthermore, both complexes exhibit strong luminescent properties in the solid state at room temperature.

机译：两种2D锌（II）层状配位聚合物化合物[Zn_2（atz）_2（na）_2] _n（1）和[Zn（atz）（ina）] _ n（2）（Hatz = 3-amino-1H-合成1，2，4-三唑，na =烟酸，ina =异烟酸），并通过元素分析，FT-IR，热重分析（TGA），粉末X射线衍射（PXRD）和单晶进行结构表征X射线衍射。共面六元六边形环和16元非平面椅子状环的互连产生具有（4，8〜2）拓扑网络的2D图纸。氢键将相邻平面连接成3D超分子体系结构。此外，两种络合物在室温下在固态下均表现出强的发光性质。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2013年第4期|共5页
作者
Gao J.-Y.; Xiong X.-H.; Chen C.-J.; Xie W.-P.; Ran X.-R.; Yue S.-T.;
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正文语种 eng
中图分类化学;
关键词
Coordination polymers; Hydrothermal synthesis; Luminescent properties; Zinc;

机译：配位聚合物;水热合成;发光性能;锌;

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1. Syntheses, structures, and fluorescence of two novel 2D zinc(II) layered frameworks based on 3-amino-1, 2, 4-triazole [J] . Gao J.-Y., Xiong X.-H., Chen C.-J., Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第3a4期

机译：基于3-amino-1，2，4-triazole的两种新型2D锌（II）层状骨架的合成，结构和荧光
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Syntheses, structures, and fluorescence of two novel 2D zinc(II) layered frameworks based on 3-amino-1, 2, 4-triazole

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