A new two-dimensional manganese(II) coordination polymer constructed from trinuclear molecular building block: Syntheses, structure and magnetic property

He C.-J.; Wang W.-Y.; Wang Y.-F.

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A new two-dimensional manganese(II) coordination polymer constructed from trinuclear molecular building block: Syntheses, structure and magnetic property

机译：由三核分子结构单元构建的新型二维锰（II）配位聚合物：合成，结构和磁性

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摘要

A new manganese(II) coordination polymer, [Mn3(atpt) _3(2, 2′-bpy)_2]_n (1) (H2atpt = 2-aminoterephthalic acid; 2, 2′-bpy = 2, 2′-bipyridine), was synthesized by hydrothermal reaction of Mn(OAc)_2, H_2atpt, and 2, 2′-bpy. It was structurally characterized by element analysis, IR spectroscopy, powder XRD, and magnetic measurements. X-ray single-crystal analysis was carried out for 1, which crystallizes in the orthorhombic system, space group Pbca. The single X-ray diffraction studies reveal that 1 consists of infinite layers of alternating trinuclear manganese subunits and H 2atpt ligands. There are two types of different coordination modes of H2atpt in 1. Magnetic susceptibility data for 1 were measured in the range 3-300 K. There are antiferromagnetic interactions between manganese ions of 1.

机译：一种新型的锰（II）配位聚合物[Mn3（atpt）_3（2，2'-bpy）_2] _n（1）（H2atpt = 2-氨基对苯二甲酸; 2，2'-bpy = 2，2'-联吡啶）是通过Mn（OAc）_2，H_2atpt和2，2'-bpy的水热反应合成的。通过元素分析，红外光谱，粉末XRD和磁测量对它进行结构表征。对1进行X射线单晶分析，该晶体在正交晶系空间群Pbca中结晶。单个X射线衍射研究表明1由无限层交替的三核锰亚基和H 2atpt配体组成。在1中，H2atpt有两种不同的配位模式。在1-300 K范围内测量了1的磁化率数据。1的锰离子之间存在反铁磁相互作用。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2013年第6期|共5页
作者
He C.-J.; Wang W.-Y.; Wang Y.-F.;
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正文语种 eng
中图分类化学;
关键词
Coordination polymers; IR spectroscopy; Magnetic properties; Manganese; X-ray diffraction;

机译：配位聚合物;红外光谱;磁性;锰;X射线衍射;

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A new two-dimensional manganese(II) coordination polymer constructed from trinuclear molecular building block: Syntheses, structure and magnetic property

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