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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >THE CRYSTAL STRUCTURES OF (NH4)(2)[RECL6], [RECL2(CH3CN)(4)](2)[RECL6]CENTER-DOT-2CH(3)CN AND [RECL4(18-CROWN-6)] [German]
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THE CRYSTAL STRUCTURES OF (NH4)(2)[RECL6], [RECL2(CH3CN)(4)](2)[RECL6]CENTER-DOT-2CH(3)CN AND [RECL4(18-CROWN-6)] [German]

机译:(NH4)(2)[RECL6],[RECL2(CH3CN)(4)](2)[RECL6] CENTER-DOT-2CH(3)CN和[RECL4(18-CROWN-6)]的晶体结构[德语]

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摘要

Brown single crystals of (NH4)(2)[ReCl6] are formed by the reaction of NH4Cl with ReCl5 in a suspension of diethylether. [ReCl2(CH3CN)(4)](2)[ReCl6] . 2CH(3)CN crystallizes as brown crystal plates from a solution of ReCl5 in acetonitrile. Lustrous green single crystals of [ReCl4(18-crown-6)] are obtained by the reaction of 18-crown-6 with ReCl5 in a dichloromethane suspension. All rhenium compounds are characterized by IR spectroscopy and by crystal structure determinations. (NH4)(2)[ReCl6]: Space group Fm
机译:(NH4)(2)[ReCl6]的棕色单晶体是通过NH4Cl与ReCl5在乙醚悬浮液中的反应形成的。 [ReCl2(CH3CN)(4)](2)[ReCl6]。 2CH(3)CN从ReCl5的乙腈溶液中结晶为棕色结晶片。 [ReCl4(18-crown-6)]的绿色光泽单晶体是通过18-crown-6与ReCl5在二氯甲烷悬浮液中的反应获得的。所有rh化合物均通过红外光谱和晶体结构测定来表征。 (NH4)(2)[ReCl6]:空间群Fm

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