Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

Xu Ning; Xing Yan; Liu Xianchun; Song Danhui; Ma Ling; Sun Xiujuan

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Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

机译：新型有机模板硫酸草酸钕（III）[C6N2H14] [Nd-2（C2O4）（2）（SO4）（2）（H2O）（4）]中心点H2O的合成，结构和光致发光特性

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An organically templated neodymium oxalate-sulfate [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. In 1, the neodymium(III) ions are interconnected through oxalate and sulfate groups to form a neodymium oxalate-sulfate hybrid structure. A luminescence spectrum of 1 was recorded, and the luminescence decay time was also measured.

机译：有机模板草酸硫酸钕[C6N2H14] [Nd-2（C2O4）（2）（SO4）（2）（H2O）（4）]中心点H2O（1）已在水热条件下合成，并且结构单一-晶体X射线衍射分析。在图1中，钕（III）离子通过草酸盐和硫酸盐基团相互连接，形成草酸钕-硫酸盐杂化结构。记录1的发光光谱，并且还测量发光衰减时间。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第3期|共5页
作者
Xu Ning; Xing Yan; Liu Xianchun; Song Danhui; Ma Ling; Sun Xiujuan;
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原文格式 PDF
正文语种 eng
中图分类 540E0007;
关键词
Neodymium; Crystal engineering; Organic-inorganic hybrid composites; Luminescence; Open framework;

机译：钕;晶体工程;有机-无机杂化复合材料;发光;开放框架;

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1. Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate [J] . Xu Ning, Xing Yan, Liu Xianchun, Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第3期

机译：新型有机模板硫酸草酸钕（III）[C6N2H14] [Nd-2（C2O4）（2）（SO4）（2）（H2O）（4）]中心点H2O的合成，结构和光致发光特性
2. Crystal structure of tetraaqua-bis(o-phthalato)-(oxalato)-dineodymium(III) monohydrate, Nd-2(H2O)(4)(C8H4O4)(2)(C2O4) center dot H2O [J] . Li YB, Zha MQ, Pan JG, Zeitschrift fur Kristallographie. New crystal structures . 2010,第1期

机译：Nd-2（H2O）（4）（C8H4O4）（2）（C2O4）中心点H2O的四水合-双（邻苯二甲酸）-（草酸酯）-二ody（III）的晶体结构
3. [C2N2H10](1.5)[Nd(SO4)3(H2O)] center dot 2H(2)O: The first organically templated neodymium sulfate with a layer structure [J] . Liu L, Meng H, Li GH, International Journal of Quantum Chemistry . 2005,第4期

机译：[C2N2H10]（1.5）[Nd（SO4）3（H2O）]中心点2H（2）O：第一种有机模板化硫酸钕，具有层状结构
4. Hydrothermal Synthesis of a New Oxalato-bridged Binuclear Complex:Cr2(bipy)4(C2O4)(SO4)2·(bipy)0.5·H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：水热合成新型草酸桥联双核络合物：Cr2（bipy）4（C2O4）（SO4）2·（bipy）0.5·H2O
5. Synthesis and crystal structure of a new polymorph of potassium europium(III) bis(sulfate) monohydrate KEu(SO4)2·H2O [O] . Avijit Kumar Paul 2018

机译：新型双水合硫酸钾potassium（KE）（SO4）2·H2O多晶型物的合成与晶体结构
6. (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type [O] . Doran, MB, Norquist, AJ, O'Hare, D 2005

机译：（C3H12N2）（2）[UO2（H2O）（2）（SO4）（2）]（2）中心点2H（2）O：具有新型二聚体类型的有机模板化硫酸铀

Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

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