Anion binding of a protonated tripodal tris(ferrocenylurea) receptor

Li M.; Wu B.; Cui F.; Hao Y.; Huang X.; Yang X.-J.

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Anion binding of a protonated tripodal tris(ferrocenylurea) receptor

机译：质子化三脚架三（二茂铁基脲）受体的阴离子结合

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Two anion complexes of a tripodal tris(ferrocenylurea) receptor (L), (LH)·CF _3SO _3 (1) and (LH)·HSO _4 (2), were obtained from L and triflic acid or sulfuric acid, respectively. Crystal structural analyses show that the receptor in the two 1:1 (host/guest) complexes is protonated (on the bridgehead tertiary amine), and the CF _3SO _3 ~- or HSO _4 ~- anion is located outside the tripodal cavity and anchored by the urea and CH groups of the receptor by hydrogen bonds. 1H NMR spectroscopic studies confirmed the binding mode in solution.

机译：三脚架三（二茂铁基脲）受体（L）的两个阴离子配合物分别是L和三氟甲磺酸或硫酸，分别是（LH）·CF _3SO _3（1）和（LH）·HSO_4（2）。晶体结构分析表明，两个1：1（主体/客体）复合物中的受体被质子化（在桥头叔胺上），CF _3SO _3〜-或HSO _4〜-阴离子位于三脚架腔外并被锚定被脲和CH基团的受体通过氢键键合。 1 H NMR光谱学研究证实了溶液中的结合模式。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2011年第15期|共6页
作者
Li M.; Wu B.; Cui F.; Hao Y.; Huang X.; Yang X.-J.;
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正文语种 eng
中图分类化学;
关键词
Anion binding; Ferrocene; NMR spectroscopy; Protonation; Tripodal tris-urea receptors;

机译：阴离子结合二茂铁核磁共振波谱质子化Tripodal tris-urea受体;

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1. Anion binding of a protonated tripodal tris(ferrocenylurea) receptor [J] . Li M., Wu B., Cui F., Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第14a15期

机译：质子化三脚架三（二茂铁基脲）受体的阴离子结合
2. Anion binding in the C_(3 v)-symmetric cavity of a protonated tripodal amine receptor: Potentiometric and single crystal X-ray studies [J] . Bose P., Ravikumar I., Ghosh P. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第21期

机译：质子化三脚架胺受体的C_（3 v）对称腔中的阴离子结合：电位和单晶X射线研究
3. Synthesis and anion binding studies of tris(3-aminopropyl)amine-based tripodal urea and thiourea receptors: proton transfer-induced selectivity for hydrogen sulfate over sulfate [J] . Khansari Maryam Emami, Johnson Corey R., Basaran Ismet, RSC Advances . 2015,第23期

机译：三（3-氨基丙基）胺基三脚架尿素和硫脲受体的合成和阴离子结合研究：质子转移诱导的硫酸氢对硫酸盐的选择性
4. Synthesis, Structure, and Binding Properties of Neutral Anion Receptors [C] . Janusz Jurczak European Symposium on Organic Chemistry . 2009

机译：中性阴离子受体的合成，结构和结合特性
5. I. The synthesis and coordination chemistry of novel 1,1,1-tris(aminomethyl)ethane (TAME) derived ligands and their use as size selective fluorescent zinc(II) sensors. II. The synthesis of strongly and weakly binding ligands with nitrogen, oxygen, and sulfur-donor groups to be used as receptors in fluorescent ratiometric indicators for transition metal ions. [D] . Kennedy, Daniel Patrick. 2007

机译：I.新型1,1,1-三（氨基甲基）乙烷（TAME）衍生的配体的合成和配位化学及其作为尺寸选择荧光锌（II）传感器的用途。二。具有氮，氧和硫供体基团的强结合和弱结合配体的合成，将用作过渡金属离子的荧光比率指示剂中的受体。
6. Synthesis and anion binding studies of tris(3-aminopropyl)amine-based tripodal urea and thiourea receptors: Proton transfer-induced selectivity for hydrogen sulfate over sulfate [O] . Maryam Emami Khansari, Corey R. Johnson, Ismet Basaran, -1

机译：三（3-氨基丙基）胺基三脚架尿素和硫脲受体的合成和阴离子结合研究：质子转移诱导的硫酸氢对硫酸盐的选择性
7. Synthesis and anion binding studies of tris(3-aminopropyl)amine-based tripodal urea and thiourea receptors: proton transfer-induced selectivity for hydrogen sulfate over sulfate [O] . Maryam Emami Khansari, Corey R. Johnson, Ismet Basaran, 2015

机译：三（3-氨基丙基）胺类三级尿素脲和硫脲受体的合成和阴离子结合研究：质子转移诱导的硫酸氢硫酸氢的选择性

Anion binding of a protonated tripodal tris(ferrocenylurea) receptor

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