From simple chalcogenidotetrelate precursors to complex structures and functional compounds

Heine J.; Dehnen S.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >From simple chalcogenidotetrelate precursors to complex structures and functional compounds

【24h】

From simple chalcogenidotetrelate precursors to complex structures and functional compounds

机译：从简单的硫属元素化合物前体到复杂的结构和功能化合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Chalcogenidotetrelates show a rich and complex chemistry encompassing intricate structures and useful materials. A step-wise coordination chemistry approach allows the sequential formation of multinary M/T/E anions (M = transition metal, T = tetrel, E = chalcogen) from simple T/E building blocks in solution. This way, a range of compounds displaying different structure types of molecular as well as extended multinary anions were obtained. To allow for even further variety, the approach can be extended to organo-functionalized chalcogenidotetrelates. Here, the organic shell of the inorganic cages plays a decisive role in reactivity and resulting structures. The formation structures and properties of these compounds will be discussed in detail in this perspective article.

机译：硫属元素半碳酸盐显示出复杂而复杂的化学结构，包括复杂的结构和有用的材料。逐步配位化学方法允许从溶液中的简单T / E结构单元按顺序形成多元M / T / E阴离子（M =过渡金属，T =蝶呤，E =硫族元素）。这样，获得了一系列显示不同结构类型的分子以及扩展的多元阴离子的化合物。为了允许进一步的变化，该方法可以扩展到有机官能化硫属元素半萜酸酯。在此，无机笼的有机壳在反应性和最终结构中起决定性作用。这些化合物的形成结构和性质将在本透视文章中详细讨论。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第15期|共16页
作者
Heine J.; Dehnen S.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Chalcogens; Cluster compounds; Group 14 elements; Hybrid compounds; Networks;

机译：硫族元素;簇化合物;第14组元素;杂化化合物;网络;

相似文献

外文文献
中文文献
专利

1. From simple chalcogenidotetrelate precursors to complex structures and functional compounds [J] . Heine J., Dehnen S. Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第15期

机译：从简单的硫属元素化合物前体到复杂的结构和功能化合物
2. Scope and limitations of the synthesis of functionalized quinolizidinones and related compounds by a simple precursor approach via addition of lithium allylmagnesates to 2-pyridones and RCM as key steps [J] . Jacek G. So?nicki, ?ukasz Struk, Tomasz Idzik, Tetrahedron . 2014,第45期

机译：通过简单的前体方法，通过将烯丙基镁酸锂添加到2-吡啶酮和RCM中，通过简单的前体方法合成功能化喹喔啉酮及其相关化合物的范围和局限性
3. SELECTIVE HYDROGENATION OF SIMPLE AND FUNCTIONALIZED CONJUGATED DIENES USING A BINUCLEAR PALLADIUM COMPLEX CATALYST PRECURSOR [J] . Cho IS., Alper H. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第32期

机译：双核钯络合物催化剂前体对简单和功能化共轭二元的选择性加氢
4. USE OF COMPLEXED AMMONIA PRECURSORS IN SYNTHESIZING LAYERED NITRIDE COMPOUNDS [C] . K. Scott Weil, Prashant N. Kumta Annual Meeting of The American Ceramic Society . 2003

机译：在合成层状氮化物化合物中使用络合氨前体
5. Green technology towards pharmaceutical drug development: I. Synthesis of differentially functionalized hydroquinone as an important pharmaceutical intermediate. II. Application in green chemistry: Environmentally friendly cleavage of aromatic ethers and trans-etherification under neutral conditions. III. Environmentally friendly simple amidation of nitro compounds: One step synthesis of acetaminophen. [D] . Tichkule, Ritesh. 2004

机译：面向药物开发的绿色技术：I.合成功能不同的对苯二酚作为重要的药物中间体。二。在绿色化学中的应用：在中性条件下对芳族醚进行环境友好的裂解和反式醚化。三，硝基化合物的环保简单酰胺化：对乙酰氨基酚的一步合成。
6. Crystal structures of bovine chymotrypsin and trypsin complexed to the inhibitor domain of Alzheimers amyloid beta-protein precursor (APPI) and basic pancreatic trypsin inhibitor (BPTI): engineering of inhibitors with altered specificities. [O] . A. J. Scheidig, T. R. Hynes, L. A. Pelletier, 1997

机译：牛胰凝乳蛋白酶和胰蛋白酶的晶体结构与阿尔茨海默氏淀粉样β蛋白前体（APPI）和碱性胰胰蛋白酶抑制剂（BPTI）的抑制剂结构域复合：特异性改变的抑制剂工程。
7. Simulation of crystal and electronic structures of octahedral molybdenum cluster complex compound Cs-2[Mo6Cl14] using various DFT functionals [O] . Saito, Norio, Lemoine, Pierric, Cordier, Stéphane, 2017

机译：使用各种DFT功能模拟八面体钼簇复合化合物Cs-2 [Mo6Cl14]的晶体和电子结构
8. Precursors of Androctonus australis Scorpion Neurotoxins. Structures of Precursors, Processing Outcomes, and Expression of a Functional Recombinant Toxin II [R] . Bougis, P. E., Rochat, H., Smith, L. A. 1989

机译：androctonus australis scorpion Neurotoxins的前体。前体结构，加工结果和功能性重组毒素II的表达

From simple chalcogenidotetrelate precursors to complex structures and functional compounds

摘要

著录项

相似文献

相关主题

期刊订阅