Hydrogen bonding network of 4-amidiniumpyridine acetate and Pt IIbis(triphenylphosphine) complexes with 4-amidinepyridine

Rigamonti L.; Carlino S.; Castellano C.; Demartin F.; Pasini A.

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Hydrogen bonding network of 4-amidiniumpyridine acetate and Pt IIbis(triphenylphosphine) complexes with 4-amidinepyridine

机译：乙酸4-ami啶吡啶和Pt IIbis（三苯基膦）配合物与4-am吡啶的氢键网络

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The X-ray structures of 4-amidiniumpyridine acetate, (1·H)AcO, and of cis-[Pt(1) _2(PPh _3) _2](NO _3) _2 (2), as well as their IR spectra, reveal intramolecular hydrogen bonding, which held together the cations and the anions. The IR spectroscopic data suggest that this may be so also in cis-[PtCl(1)(PPh _3) _2](BF _4) (3). In (1·H)AcO and in 2 extensive intermolecular hydrogen bonding networks span through the whole crystals.

机译：乙酸4-ami基吡啶（1·H）AcO和顺式-[Pt（1）_2（PPh _3）_2]（NO _3）_2（2）的X射线结构及其红外光谱，揭示分子内氢键，将阳离子和阴离子结合在一起。红外光谱数据表明，在顺式[PtCl（1）（PPh _3）_2]（BF _4）中也可能如此（3）。在（1·H）AcO和2个广泛的分子间氢键网络贯穿整个晶体。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第14期|共5页
作者
Rigamonti L.; Carlino S.; Castellano C.; Demartin F.; Pasini A.;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
4-Amidiniumpyridine; Crystal structure; Hydrogen bonds; Platinum;

机译：4-A基吡啶;晶体结构;氢键;铂;

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1. Hydrogen bonding network of 4-amidiniumpyridine acetate and Pt IIbis(triphenylphosphine) complexes with 4-amidinepyridine [J] . Rigamonti L., Carlino S., Castellano C., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第14期

机译：乙酸4-ami啶吡啶和Pt IIbis（三苯基膦）配合物与4-am吡啶的氢键网络
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Hydrogen bonding network of 4-amidiniumpyridine acetate and Pt IIbis(triphenylphosphine) complexes with 4-amidinepyridine

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