Synthesis, structures, and CO releasing properties of two tricarbonyl manganese(I) complexes

Mohr F.; Niesel J.; Schatzschneider U.; Lehmann C.W.

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Synthesis, structures, and CO releasing properties of two tricarbonyl manganese(I) complexes

机译：两种三羰基锰（I）配合物的合成，结构和CO释放特性

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[MnBr(CO) _5] reacts with one equivalent each of 1, 3, 5-triaza-7-phosphaadamantane (PTA) and sodium diethyldithiocarbamate to afford the yellow Mn ~I complex fac-[Mn(S _2CNEt _2)(PTA) (CO) _3]. Similarly, the same Mn ~I precursor reacts with the sodium salt ofL-histidine to give the tricarbonyl manganese(I) complex fac-[Mn(his)(CO) _3] in good yield as a yellow solid. Both compounds were spectroscopically and structurally characterised. The histidinato complex is soluble in water and its aqueous solutions are stable for more than 24 h. The CO releasing properties of the histidinato complex were studied with the myoglobin assay and establish this compound as a novel PhotoCORM, which liberates one of the three carbonyl ligands upon irradiation.

机译：[MnBr（CO）_5]与1、3、5-triaza-7-phosphaadamantane（PTA）和二乙基二硫代氨基甲酸钠中的一种当量反应，得到黄色的Mn〜I络合物fac- [Mn（S _2CNEt _2）（PTA）（CO）_3]。类似地，相同的Mn〜I前体与L-组氨酸的钠盐反应，以黄色固体状良好收率得到三羰基锰（I）配合物fac- [Mn（his）（CO）_3]。两种化合物均经过光谱和结构表征。 Histidinato复合物可溶于水，其水溶液稳定超过24小时。用肌红蛋白测定法研究了组氨酸的复合物的CO释放特性，并将该化合物确立为新型PhotoCORM，该化合物在辐照后释放出三个羰基配体之一。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第4期|共4页
作者
Mohr F.; Niesel J.; Schatzschneider U.; Lehmann C.W.;
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正文语种 eng
中图分类化学;
关键词
Carbonyl complexes; CO releasing molecules; Manganese; Water soluble organometallic compounds; X-ray diffraction;

机译：羰基配合物;CO释放分子;锰;水溶性有机金属化合物;X射线衍射;

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Synthesis, structures, and CO releasing properties of two tricarbonyl manganese(I) complexes

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