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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis, crystal structure, and magnetic properties of TbAl3Cl12 [German]
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Synthesis, crystal structure, and magnetic properties of TbAl3Cl12 [German]

机译:TbAl3Cl12的合成,晶体结构和磁性[德国]

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摘要

TbAl3Cl12 was synthesized and the crystal structure was determined from single crystal X-ray diffraction data for the first time, The compound crystallizes trigonally in space group P3(1)12 with a = 10-49.8(1) and c = 1567.3(2) pm. Terbium cations are located in quadratic antiprisms of chloride anions, Magnetic measurements were performed to study the interactions between Tb3+ and Cl-. Magnetic data were interpreted by ligand field calculations applying the angular overlap model. [References: 22]
机译:合成了TbAl3Cl12,并首次从单晶X射线衍射数据确定了晶体结构。该化合物在空间群P3(1)12中三角结晶,a = 10-49.8(1),c = 1567.3(2)下午。 b阳离子位于氯离子的二次反棱镜中,进行磁测量以研究Tb3 +与Cl-之间的相互作用。磁数据通过应用角重叠模型的配体场计算来解释。 [参考:22]

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