Reactions of the dielement compounds R2E-ER2 [E = Ga, In; R = CH(SiMe3)(2)] with lithium phenylethynide - Formation of adducts by retention of the E-E bonds [German]

Uhl W.; Spies T.

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Reactions of the dielement compounds R2E-ER2 [E = Ga, In; R = CH(SiMe3)(2)] with lithium phenylethynide - Formation of adducts by retention of the E-E bonds [German]

机译：二元化合物R2E-ER2的反应R = CH（SiMe3）（2）]和苯乙炔锂-通过保留E-E键形成加合物[德国]

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Lithium phenylethynide reacted with the dielement compounds tetrakis[bis(trimethylsilyl)methyl]digallane(4) (2) and diindane(4) (3) as a Lewis-base and gave by the addition of one ethynido ligand to one of the Lewis-acidic central atoms the anionic adducts 4 and 5 with intact Ga-Ga and In-In single bonds. Thus, compounds were formed, in which tricoordinated, coordinatively unsaturated Ga or In atoms are neighbored to tetracoordinated, coordinatively saturated ones. The E-E bonds [255.83 pm in 4 (Ga-Ga) and 285.24 pm in 5 (In-In)] are only slightly lengthened compared to those of the starting compounds 2 and 3. A dynamic behavior with a fast change of the position of the ethynido ligand was observed for both compounds in solution at room temperature. [References: 41]

机译：苯基乙炔锂与路易斯化合物的四[双（三甲基甲硅烷基）甲基] digallane（4）（2）和diindane（4）（3）等二元化合物反应，并通过向路易斯-之一中添加一个乙炔基配体得到带有酸性中心原子的阴离子加合物4和5，具有完整的Ga-Ga和In-In单键。因此，形成了其中三配位，配位不饱和的Ga或In原子与四配位，配位饱和的原子相邻的化合物。 EE键[4（Ga-Ga）中的255.83 pm和5（In-In）中的285.24 pm]与起始化合物2和3相比仅略微延长了。在室温下观察到两种化合物的乙炔基配体。 [参考：41]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2000年第5期|共6页
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Uhl W.; Spies T.;
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正文语种 ger
中图分类化学;
关键词
Gallium; Indium; E-e bonds; Al-al bond; Aluminum aluminum bond; In-in bond; R(2)al-alr(2) r=ch(sime(3))(2); Substituent exchange; Monomeric compounds; Chalcogen atoms; Insertion; Single; Tetrakislt; bis(trimethylsilyl)methylgt; digallane(4);

机译：镓;铟;Ee键;Al-al键;铝铝键;In-in键;R（2）al-alr（2）r = ch（sime（3））（2）;取代基交换;单体化合物;硫族元素原子;插入;单;四（二甲基）（四）;

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1. Reactions of the dielement compounds R2E-ER2 [E = Ga, In; R = CH(SiMe3)(2)] with lithium phenylethynide - Formation of adducts by retention of the E-E bonds [German] [J] . Uhl W., Spies T. Zeitschrift fur Anorganische und Allgemeine Chemie . 2000,第5期

机译：二元化合物R2E-ER2的反应R = CH（SiMe3）（2）]和苯乙炔锂-通过保留E-E键形成加合物[德国]
2. Reactions of tetraaklyldiindane(4), R2In-InR2 (R = CH(SiMe3)(2)), with tert-butyl and phenyl isonitriles. Formation of adducts with retention of the In-In bond [J] . Uhl W., Wartchow R., Hannemann F. Organometallics . 1998,第17期

机译：四烷基二茚满（4），R2In-InR2（R = CH（SiMe3）（2））与叔丁基和苯基异腈的反应。保留In-In键形成加合物
3. Reactions of the tetraalkyldigallium compound R_2Ga-GaR _2 [R = CH(SiMe_3)_2] with acidic reagents, retention vs. cleavage of the Ga-Ga bond and formation of supramolecular aggregates via hydrogen bonding [J] . Uhl W., Vo? M., Hepp A. Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第12期

机译：四烷基dig化合物R_2Ga-GaR_2 [R = CH（SiMe_3）_2]与酸性试剂的反应，Ga-Ga键的保留与裂解以及通过氢键形成超分子聚集体
4. Lithium Perchlorate / Nitromethane as an Effective Electrochemical Reaction Medium for the Intermolecular C-C Bond Formations [C] . Kazuhiro Chiba The Meeting of the Electrochemical Society . 2000

机译：高氯酸锂/硝基甲烷作为分子间C-C键形成的有效电化学反应介质
5. THE ACTIVATION OF ALKYNES TOWARD CARBON-CARBON BOND FORMATION AND CARBON-CARBON BOND CLEAVAGE IN THEIR REACTIONS WITH TUNGSTEN(2)(OR)(6)L(X) COMPOUNDS [D] . CONROY, BRIAN K. 1987

机译：钨（2）（或）（6）L（X）化合物反应中烷基向碳-碳键形成的活化和碳-碳键的裂解
6. Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands for Main Group and Transition Metals: κ2-NN Coordination S-S Bond Cleavage and S-S/E-E (E = S Se) Bond Metathesis Reactions [O] . Joshua S. Figueroa, Kevin Yurkerwich, Jonathan Melnick, -1

机译：双（1-R-咪唑-2-基）二硫化物和二硒化物作为主族和过渡金属的配体的应用：κ2-NN配位SS键断裂和SS / EE（E = SSe）键复分解反应
7. Reaktionen des metalloiden Clusteranions {Ge9Si(SiMe3)33}- in der Gasphase. Oxidations- und Reduktionsschritte geben Einblicke in den Bereich zwischen metalloiden Clustern und Zintl-Ionen. Reactions of the Metalloid Cluster Anion {Ge9Si(SiMe3)33}- in [O] . Christian Schenk, Florian Henke, Marco Neumaier, 2010

机译：金属粒子膜的反应{Ge9 Si（SiMe3）3 3} - 在气相中。氧化和还原步骤对金属簇和Zintl离子之间的区域提供洞察。金属聚类阴离子的反应{GE9 SI（SIME3）3 3} - IN
8. Reaction of LiE(SiMe3)2 with Compounds Containing Four-Measured Cores of the General Formula MEMCl (M = In, E = As, P; M = Ga, E = As): Novel Rearrangement Reactions to Form the Adducts R3M.As(SiMe3)3 (R = Me3SiCH2, M = In; R = Ph, M = Ga). [R] . Wells, R. L., McPhail, A. T., Jones, L. J., 1992

机译：LiE（sime3）2与含有通式mEmCl的四个测量核的化合物（m = In，E = as，p; m = Ga，E = as）的反应：形成加合物R3m.as的新型重排反应（ sime3）3（R = me3siCH2，m = In; R = ph，m = Ga）。

Reactions of the dielement compounds R2E-ER2 [E = Ga, In; R = CH(SiMe3)(2)] with lithium phenylethynide - Formation of adducts by retention of the E-E bonds [German]

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