Trifluoromethyl nitrate, CF3ONO2 [German]

Sander S.; Oberhammer H.; Arguello GA.; Willner H.

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Trifluoromethyl nitrate, CF3ONO2 [German]

机译：硝酸三氟甲酯，CF3ONO2 [德语]

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From different routes to CF3ONO2, the reaction of CF3OF with NO2 at room temperature under high pressure is the most favorable to synthesize CF3ONO2 in preparative scale. The pure product is isolated for the first time after repeated trap-to-trap condensation in vacuo. CF3ONO2 is a colourless gas with a boiling point of -18 +/- 3 degreesC (extrapol.) and a melting point of -163 degreesC. Trifluoromethyl nitrate decays slowly into CF2O and FNO2 at room temperature in the gas phase as well as in the liquid state at lower temperatures. Furthermore, CF3ONO2 is characterized spectroscopically by NMRI IR, Raman, and UV, and structurally by gas electron diffraction and quantum chemical calculations (B3LYP. MP2). The CF3-O bond is in the plane of the NO3 moiety, the central CF3O-NO2 bond of 1.493(6)(A) over dot is very long. The B3LYP/6-31G* calculation reproduces best the experimental data. [References: 31]

机译：从不同的途径到CF3ONO2，CF3OF与NO2在室温，高压下的反应是最有利于制备规模的CF3ONO2的方法。在真空中反复捕集阱凝结后，首次分离出纯产物。 CF 3 ONO 2是一种无色气体，其沸点为-18 +/- 3℃（极高），熔点为-163℃。硝酸三氟甲基甲烷在室温下在气相中以及在较低温度下在液态时缓慢地分解为CF2O和FNO2。此外，CF3ONO2在光谱上通过NMRI IR，拉曼光谱和UV表征，在结构上通过气相电子衍射和量子化学计算（B3LYP。MP2）表征。 CF3-O键位于NO3部分的平面内，点上的1.493（6）（A）中心CF3O-NO2键很长。 B3LYP / 6-31G *计算可以最好地再现实验数据。 [参考：31]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2001年第4期|共7页
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Sander S.; Oberhammer H.; Arguello GA.; Willner H.;
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1. Trifluoromethyl nitrate, CF3ONO2 [German] [J] . Sander S., Oberhammer H., Arguello GA., Zeitschrift fur Anorganische und Allgemeine Chemie . 2001,第4期

机译：硝酸三氟甲酯，CF3ONO2 [德语]
2. Bonding properties of siloxanes: Gas phase structures of N,N-bis(trifluoromethyl)-O-(trimethylsilyl)hydroxylamine, Me3SiON(CF3)(2), and trimethylsilyl nitrate, Me3SiONO2 [J] . Hertel T., Minkwitz R., Oberhammer H., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第20期

机译：硅氧烷的键合性质：N，N-双（三氟甲基）-O-（三甲基甲硅烷基）羟胺Me3SiON（CF3）（2）和三甲基甲硅烷基硝酸盐Me3SiONO2的气相结构
3. Germany AMMONIUM NITRATES/NITRATE [J] . Argus FMB Weekly Report Group Argus FMB Weekly Report . 2016,第29期

机译：德国硝酸铵/硝酸铵
4. Natural attenuation of common agricultural and atmospheric pollutants: reactive transport of nitrate, potassium and aluminium in sandy sediments of northwestern Germany [C] . GEORG J. HOUBENauthor_name/, International Association of Hydrological Sciences, IAHS Publication No.275, Groundwater quality conference . 2002

机译：普通农业和大气污染物的自然衰减：德国西北砂沉积物硝酸盐，钾和铝的反应运输
5. Matrix Isolation of Aryl(trifluoromethyl)carbenes, Heteroaryl(trifluoromethyl)carbenes and Phenylbis(trifluoromethyl)carbenes. [D] . Wang, Pei. 2015

机译：芳基（三氟甲基）卡宾，杂芳基（三氟甲基）卡宾和苯基双（三氟甲基）卡宾的基质分离。
6. Acid catalyzed cyclodimerization of 22-bis(trifluoromethyl)-4-alkoxy-oxetanes and -thietanes. Synthesis of 2266-tetrakis(trifluoromethyl)-48-dialkoxy-15-dioxocanes and 3377-tetrakis(trifluoromethyl)-9-oxa-26-dithia-bicyclo3.3.1nonane [O] . Viacheslav A Petrov, Will Marshall 2010

机译：酸催化22-双（三氟甲基）-4-烷氧基-氧杂环丁烷和-硫杂环丁烷的环二聚。 2266-四（三氟甲基）-48-二烷氧基-15-二氧杂环丁烷和3377-四（三氟甲基）-9-oxa-26-dithia-的合成双环3.3.1壬烷
7. Nitrate and sulfate isotopes in the groundwater of the sandy Haltern Formation (Germany) to investigate nitrate reduction processes : 078 [O] . Wisotzky, Frank, Leson, Martin, Banning, Andre 2013

机译：盐卤岩层（德国）地下水中的硝酸盐和硫酸盐同位素，用于研究硝酸盐的还原过程：078
8. 16.REACTIONS OF TRIFLUOROMETHYL HYPOFLUORITE WITH ORGANIC COMPOUNDS 17.THERMAL DECOMPOSITION OF FLUORINE NITRATE 18.ARSENYL FLUORIDE [R] . John A. C. Allison, William Eugene Skiens, Grihapati Mitra 1957

机译：16.三氟甲基次磷酸盐与有机化合物的反应17.硝酸氟的热分解18.aRsENYL FLORORIDE

Trifluoromethyl nitrate, CF3ONO2 [German]

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