REACTIONS OF TETRAALKYL DIALUMINIUM(4), DIGALLIUM(4) AND DIINDIUM(4) COMPOUNDS WITH 3-CHLOROPERBENZOIC ACID - CLEAVAGE OF THE ELEMENT-ELEMENT BONDS AND FORMATION OF MU-CARBOXYLATO-O,O'-MU-HYDROXO DIELEMENT DERIVATIVES [German]

Uhl W.; Hahn I.; Graupner R.

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REACTIONS OF TETRAALKYL DIALUMINIUM(4), DIGALLIUM(4) AND DIINDIUM(4) COMPOUNDS WITH 3-CHLOROPERBENZOIC ACID - CLEAVAGE OF THE ELEMENT-ELEMENT BONDS AND FORMATION OF MU-CARBOXYLATO-O,O'-MU-HYDROXO DIELEMENT DERIVATIVES [German]

机译：四烷基二（4），二（4）和二（4）化合物与3-氯过苯甲酸的反应-元素键的裂解和MU-羧基-O，O'-MU-羟基金属衍生物的形成]

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Tetrakis [bis(trimethylsilyl)methyl] dialane(4) 1, -digallane(4) 2 und -diindane(4) 3 with the elements Al, Ga, and In in the unusual oxidation state of +2 react with 3-chloroperbenzoic acid by the cleavage of their element-element single bonds. As shown by crystal structure determinations of the Ga (5) and In derivative (6), the products exhibit two dialkylelement fragments bridged by a mu-hydroxo and a mu-carboxylato-O,O' group in the solid state. Their formation can be described by an insertion of the low valent Al, Ga, or In atoms into the peroxo group. Only the constitution of the Al compound 4 remains unchanged in solution, while the Ga and In analogs partially dissociate to form the compounds R2E(mu-OH)(2)ER2 and R2E(O2CR') (E = Ga or In, R=CH(SiMe3)(2), R'=-3-Cl-C6H4), which all were synthesized and isolated in a pure form by other routes. [References: 54]

机译：四价[双（三甲基甲硅烷基）甲基]二烷（4）1-地没烷（4）2和-二茚满（4）3与元素Al，Ga和In处于异常的+2氧化态与3-氯过苯甲酸反应通过裂解它们的元素单键。如通过Ga（5）和In衍生物（6）的晶体结构确定所示，产物显示出两个由固态的mu-hydroxo和mu-羧基-O，O'基桥接的二烷基元素片段。它们的形成可以通过将低价的Al，Ga或In原子插入到过氧基团中来描述。仅Al化合物4的组成在溶液中保持不变，而Ga和In类似物部分解离形成化合物R2E（mu-OH）（2）ER2和R2E（O2CR'）（E = Ga或In，R = CH（SiMe3）（2），R'=-3-Cl-C6H4），它们都是通过其他途径合成并以纯净形式分离的。 [参考：54]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第4期|共8页
作者
Uhl W.; Hahn I.; Graupner R.;
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中图分类化学;
关键词
Al-al bond; Ga-ga bond; In-in bond; Reaction with perbenzoic acid; Mu-hydroxo and mu-carboxylato groups; Molecular-structure; Crystal-structure; Coordination chemistry; Tert-butylaluminum; Aluminum; Hydrolysis; Gallium; )t-bu2ga(mu-oh)gt; 3; Alkylalumoxanes; Decomposition;

机译：Al-al键;Ga-ga键;in-in键;与过苯甲酸反应;Mu-羟基和μ-羧基;分子结构;晶体结构;配位化学;叔丁基铝;铝;水解;镓;）t-bu2ga（mu-oh） 3;烷基铝氧烷;分解;

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1. REACTIONS OF TETRAALKYL DIALUMINIUM(4), DIGALLIUM(4) AND DIINDIUM(4) COMPOUNDS WITH 3-CHLOROPERBENZOIC ACID - CLEAVAGE OF THE ELEMENT-ELEMENT BONDS AND FORMATION OF MU-CARBOXYLATO-O,O'-MU-HYDROXO DIELEMENT DERIVATIVES [German] [J] . Uhl W., Hahn I., Graupner R. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第4期

机译：四烷基二（4），二（4）和二（4）化合物与3-氯过苯甲酸的反应-元素键的裂解和MU-羧基-O，O'-MU-羟基金属衍生物的形成]
2. Reactions of the digallium compound R_2Ga-GaR_2 [R = CH(SiMe_3)_2] with water and carboxylic acids - synthesis of μ-hydroxo-μ-carboxylatodigallium compounds with retention of the Ga-Ga bonds [Reaktionen der digalliumverbindung R_2Ga-GaR_2 [R = CH(SiMe_3)_2] mit wasser und carbons?uren - synthese von μ-hydroxo-μcarboxylatodigallium-verbindungen unter erhalt der Ga-Ga-bindungen] [J] . Uhl W., Bock H.R., Hepp A., Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第7期

机译：双镓化合物R_2Ga-GaR_2 [R = CH（SiMe_3）_2]与水和羧酸的反应-保留Ga-Ga键的μ-羟基-μ-羧基二叠氮化镓化合物的合成[双镓化合物R_2Ga-GaR_2的反应[R =带有水和羧酸的CH（SiMe_3）_2]-在保留Ga-Ga键的情况下合成μ-羟基-μ羧基二茂金属化合物]
3. Reactions of the tetraalkyldigallium compound R_2Ga-GaR _2 [R = CH(SiMe_3)_2] with acidic reagents, retention vs. cleavage of the Ga-Ga bond and formation of supramolecular aggregates via hydrogen bonding [J] . Uhl W., Vo? M., Hepp A. Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第12期

机译：四烷基dig化合物R_2Ga-GaR_2 [R = CH（SiMe_3）_2]与酸性试剂的反应，Ga-Ga键的保留与裂解以及通过氢键形成超分子聚集体
4. Nickel-Catalyzed Cross-Coupling Reaction of Anisole Derivatives with Organoboron Compounds via C-O Bond Cleavage [C] . Mamoru Tobisu, Toshiaki Shimasaki, Naoto Chatani Symposium on Organometallic Chemistry . 2008

机译：通过C-O键裂解镍催化偶氧衍生物与有机硼化合物的交叉偶联反应
5. THE ACTIVATION OF ALKYNES TOWARD CARBON-CARBON BOND FORMATION AND CARBON-CARBON BOND CLEAVAGE IN THEIR REACTIONS WITH TUNGSTEN(2)(OR)(6)L(X) COMPOUNDS [D] . CONROY, BRIAN K. 1987

机译：钨（2）（或）（6）L（X）化合物反应中烷基向碳-碳键形成的活化和碳-碳键的裂解
6. A study of the formation of fluorescent derivatives of 4-hydroxyphenethylamine (tyramine) 4-hydroxy-3-methoxyphenethylamine (3-methoxytyramine) and related compounds by reaction with hydrazine in the presence of nitrous acid [O] . P. H. Scott 1971

机译：亚硝酸存在下与肼反应生成4-羟基苯乙胺（酪胺）4-羟基-3-甲氧基苯乙胺（3-甲氧基酪胺）及相关化合物的荧光衍生物的研究
7. Acid-catalyzed tandem reaction for the synthesis of pyridine derivatives via CC/C(sp3)–N bond cleavage of enones and primary amines [O] . Zhong-Yuan Mao, Xiao-Yun Liao, Heng-Shan Wang, 2017

机译：酸催化的串联反应，用于合成吡啶衍生物的C 1 C / C（SP3）-N粘结粘膜和原发性胺

REACTIONS OF TETRAALKYL DIALUMINIUM(4), DIGALLIUM(4) AND DIINDIUM(4) COMPOUNDS WITH 3-CHLOROPERBENZOIC ACID - CLEAVAGE OF THE ELEMENT-ELEMENT BONDS AND FORMATION OF MU-CARBOXYLATO-O,O'-MU-HYDROXO DIELEMENT DERIVATIVES [German]

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