A new 3D supramolecular manganese(II) complex constructed from benzimidazole-5,6-dicarboxylate and Oxalate: Synthesis, structural, and magnetic properties

Geng J.-P.; Wang Z.-X.; Wu Q.-F.; Li M.-X.; Xiao H.-P.

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A new 3D supramolecular manganese(II) complex constructed from benzimidazole-5,6-dicarboxylate and Oxalate: Synthesis, structural, and magnetic properties

机译：由5,6-二羧酸苯并咪唑和草酸酯构成的新型3D超分子锰（II）配合物：合成，结构和磁性

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摘要

A new manganese(II) complex [Mn_3(bidc)_2(C _2O_4)(H_2O)_(10)]_n (1) (bidc = benzimidazole-5,6-dicarboxylate) was synthesized and characterized by X-ray crystallography. X-ray diffraction shows that complex 1 has a neutral, one-dimensional (1D) brick wall chain structure. With the intramolecular and intermolecular hydrogen bonding interactions, the adjacent chains are joined into a 3D suparmolecular architecture. IR spectroscopy and variable temperature magnetic susceptibility measurements were made, which indicated weak antiferromagnetic coupling between the MnII ions in complex 1.

机译：合成了新的锰（II）配合物[Mn_3（bidc）_2（C _2O_4）（H_2O）_（10）] _ n（1）（bidc =苯并咪唑-5,6-二羧酸酯），并通过X射线晶体学对其进行了表征。 X射线衍射表明配合物1具有中性的一维（1D）砖墙链结构。通过分子内和分子间的氢键相互作用，相邻的链连接成3D超分子结构。进行了红外光谱和可变温度磁化率测量，表明复合物1中MnII离子之间的弱反铁磁耦合。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2011年第2期|共5页
作者
Geng J.-P.; Wang Z.-X.; Wu Q.-F.; Li M.-X.; Xiao H.-P.;
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正文语种 eng
中图分类化学;
关键词
Benzimidazole-5; 6-dicarboxylate acid; IR spectroscopy; Magnetic properties; Manganese; X-ray diffraction;

机译：苯并咪唑-5;6-二羧酸;红外光谱;磁性;锰;X射线衍射;

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A new 3D supramolecular manganese(II) complex constructed from benzimidazole-5,6-dicarboxylate and Oxalate: Synthesis, structural, and magnetic properties

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