Four dysprosium(III) compounds based on 1H-benzimidazole-5,6-dicarboxylic acid via hydrothermal synthesis

Sun Y.-G.; Xiong G.; Guo M.-Y.; Ding F.; Wang L.; Gao E.-J.; Zhu M.-C.; Verpoort F.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Four dysprosium(III) compounds based on 1H-benzimidazole-5,6-dicarboxylic acid via hydrothermal synthesis

【24h】

Four dysprosium(III) compounds based on 1H-benzimidazole-5,6-dicarboxylic acid via hydrothermal synthesis

机译：水热合成基于1H-苯并咪唑-5,6-二羧酸的四种（III）化合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Four compounds [Dy(H2bidc)(Hbidc)(H_2O)_8] ·8H_2O (1), {[Dy(Hbidc)(H_2O)_2(Htzac)] ·3H_2O}_n (2), [Dy(C_2O_4) _(0.5)(Hbidc)(H_2O)_3]_n (3), {[Dy _2(Hbidc)_2(H_2O)(SO_4)] ·H _2O}_n (4) (H_3bidc = 1H-benzimidazole-5,6- dicarboxylic acid, H_2tzac = 1H-3-amino-5-carboxy-1,2,4-triazole) were synthesized with hydrothermal synthesis and structurally characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. X-ray analysis revealed that the four coordination compounds have different structures: Compound 1 is a three dimensional supermolecular structure joined by hydrogen bonding interactions based upon dinuclear units. Compound 2 is a three dimensional supermolecular structure combined by hydrogen-bonding interactions based upon one dimensional coordination chain including a T4(1)-type water cluster chain. The structure of compound 3 is built of two dimensional (3,6)-connected kgd-type (4~3)_2(4~6.6 ~6.8~3) layers with a right-handed and a left-handed helical chain, which are further extended into three dimensional supramolecular architecture by hydrogen bonding interactions. Compound 4 displays a three dimensional framework containing a dinuclear dysprosium building unit with a (3,8)-connected (4.5~2)_2(4~2.5 ~(10).6~(12).7.8~3) topological framework. In addition, the photoluminescent property of compound 3 was investigated.

机译：四种化合物[Dy（H2bidc）（Hbidc）（H_2O）_8]·8H_2O（1），{[Dy（Hbidc）（H_2O）_2（Htzac）]·3H_2O} _n（2），[Dy（C_2O_4）_（ 0.5）（Hbidc）（H_2O）_3] _n（3），{[Dy _2（Hbidc）_2（H_2O）（SO_4）]·H _2O} _n（4）（H_3bidc = 1H-苯并咪唑-5,6-二羧酸通过水热合成法合成了酸（H_2tzac = 1H-3-氨基-5-羧基-1,2,4-三唑），并通过元素分析，红外光谱和单晶X射线衍射对其结构进行了表征。 X射线分析表明，四种配位化合物具有不同的结构：化合物1是三维双分子结构，通过基于双核单元的氢键相互作用而结合在一起。化合物2是基于包括T4（1）型水簇链的一维配位链通过氢键相互作用结合而成的三维超分子结构。化合物3的结构是由两维（3,6）连接的kgd型（4〜3）_2（4〜6.6〜6.8〜3）层构成的，该层具有右旋和左旋螺旋链，通过氢键相互作用进一步扩展为三维超分子结构。化合物4显示了三维框架，其中包含具有（3,8）连接的（4.5〜2）_2（4〜2.5〜（10）.6〜（12）.7.8〜3）拓扑框架的双核di构建单元。另外，研究了化合物3的光致发光性质。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2011年第2期|共8页
作者
Sun Y.-G.; Xiong G.; Guo M.-Y.; Ding F.; Wang L.; Gao E.-J.; Zhu M.-C.; Verpoort F.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Coordination modes; Dysprosium; Framework structures; Hydrothermal synthesis; IR spectroscopy;

机译：配位模式y骨架结构水热合成红外光谱;

相似文献

外文文献
中文文献
专利

1. Four dysprosium(III) compounds based on 1H-benzimidazole-5,6-dicarboxylic acid via hydrothermal synthesis [J] . Sun Y.-G., Xiong G., Guo M.-Y., Zeitschrift fur Anorganische und Allgemeine Chemie . 2011,第2期

机译：水热合成基于1H-苯并咪唑-5,6-二羧酸的四种（III）化合物
2. Hydrothermal synthesis, crystal structure and properties of Ni(ii)-4f complexes based on 1H-benzimidazole-5,6-dicarboxylic acid [J] . Sun Y.-G., Xiong G., Guo M.-Y., Dalton transactions: An international journal of inorganic chemistry . 2012,第25期

机译：1H-苯并咪唑-5,6-二羧酸的Ni（ii）-4f配合物的水热合成，晶体结构和性能
3. Two novel d(10) transition metal complexes based on 1H-benzimidazole-5,6-dicarboxylic acid: Synthesis, structure and multifunctional luminescence detection [J] . Liu Chun-Hong, Xing Shang-Hua, Zhou Jun, Applied Organometallic Chemistry . 2019,第10期

机译：基于1H-苯并咪唑-5,6-二羧酸的两种新型D（10）过渡金属配合物：合成，结构和多官能发光检测
4. Synthesis and Properties of Polymers Based on N-Vinyl-Pyrrolidone and Halogen-Containing Compounds of Acrylic Acids [C] . Malkanduev Yusuf A, Begieva Madina B, Kokoeva Aneta A. International scientific and practical conference «New Polymer Composite Materials» . 2020

机译：基于N-乙烯基 - 吡咯烷酮和含卤素酸化合物的聚合物的合成与性能
5. Manganese(III)-based oxidative cyclizations: Formal synthesis of 15-acetoxypallescensin A. Synthesis of hindered guanidines. Completion of the total synthesis of martinellic acid. [D] . O'Hare, Sean Matthew. 2002

机译：基于锰（III）的氧化环化：15-乙酰氧基palscensin A的正式合成。受阻胍的合成。完成马汀酸的全合成。
6. Bis26-bis(1H-pyrazol-1-yl)pyridinedecakis(μ2-3-nitrobenzoato)bis(3-nitrobenzoato)tetradysprosium(III): a linear tetranuclear dysprosium compound based on mixed N- and O-donor ligands [O] . Rong Hua, Xiao-Liu Wu, Jin-Ying Li 2014

机译：双26-双（1H-吡唑-1-基）吡啶癸基（μ2-3-硝基苯并）双（3-硝基苯并）四dy（III）：基于混合N-和O-的线性四核化合物供体配体
7. Different complexation behavior of a proton transfer compound obtained from 1,10-phenanthroline and pyridine-2,6-dicarboxylic acid with In^III and Ce^III: Synthesis, crystal structures and solution studies [O] . Ramezanipour, Farshid, Aghabozorg, Hossein, Shokrollahi, Ardeshir, 2009

机译：1,10-菲咯啉和2,6-吡啶二甲酸吡啶与In ^{III 和Ce ^{III 制备的质子转移化合物的不同络合行为：合成，晶体结构和结构解决方案研究}}
8. Search for Radioprotective Compounds. Part XVIII. Synthesis and Protective Activity of a Series of S-Omega(Omega-(Omega-Aminoalkylamino) Alkylamino) Alkylphosphorothioic Acids and Disulphides [R] . Grant, G. A., Sowa, W., Licht, B. A., 1980

机译：寻找辐射防护化合物。第十八部分。一系列s-Omega（ω-（ω-氨基烷基氨基）烷基氨基）烷基硫代磷酸和二硫化物的合成及保护活性

Four dysprosium(III) compounds based on 1H-benzimidazole-5,6-dicarboxylic acid via hydrothermal synthesis

摘要

著录项

相似文献

相关主题

期刊订阅