Synthesis, crystal structure and properties of Li _2Cu _5(PO _4) _4

Snyder K.; Glaum R.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis, crystal structure and properties of Li _2Cu _5(PO _4) _4

【24h】

Synthesis, crystal structure and properties of Li _2Cu _5(PO _4) _4

机译：Li _2Cu _5（PO _4）_4的合成，晶体结构与性能

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Li _2Cu ~II _5(PO _4) _4 has been obtained by various reactions starting from copper or Cu _2O. Crystallization was achieved using I _2 as oxidant and mineralizer. The new orthophosphate crystallizes in space group P1?, Z = 2, with a = 6.0502(3) ?, b = 9.2359(4) ?, c = 11.4317(5) ?, α = 75.584(2)°, β = 80.260(2)°, γ = 74.178(2)°, at 293 K. Its structure has been determined from X-ray single-crystal data and refined to R _1 = 0.022{wR _2 = 0.058 for 4633 unique reflections with F _o > 4σ (F _o)}. From magnetic measurements μ _(eff) = 1.51 μ _B/Cu and θ _P = -37.4 K have been determined. The Vis/NIR spectrum of aqua-green Li _2Cu _5(PO _4) _4 shows a single broad band centered around 1? = 12000 cm ~(-1). Magnetic behavior and spectrum are discussed within the angular overlap model.

机译：Li _2Cu〜II _5（PO _4）_4已通过各种反应从铜或Cu _2O开始获得。使用I _2作为氧化剂和矿化剂实现了结晶。新的正磷酸盐在空间群P1β中结晶，Z = 2，a = 6.0502（3）β，b = 9.2359（4）β，c = 11.4317（5）β，α= 75.584（2）°，β= 80.260 （2）°，在293 K时的γ= 74.178（2）°。已根据X射线单晶数据确定了其结构，并针对F _o> 4σ（F _o）}。从磁测量中，已经确定μ_（eff）= 1.51μ_B / Cu和θ_P = -37.4K。水绿色Li _2Cu _5（PO _4）_4的Vis / NIR光谱显示一个以1？为中心的宽带。 = 12000厘米〜（-1）。在角度重叠模型中讨论了磁行为和频谱。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2012年第9期|共6页
作者
Snyder K.; Glaum R.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Cathode material; Lithium; Phosphate; Solid-state chemistry; Solid-state structures;

机译：阴极材料锂磷酸盐固态化学固态结构;

相似文献

外文文献
中文文献
专利

1. Synthesis, crystal structure and properties of Li _2Cu _5(PO _4) _4 [J] . Snyder K., Glaum R. Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第9期

机译：Li _2Cu _5（PO _4）_4的合成，晶体结构与性能
2. Synthesis, crystal structure, transport, and magnetic properties of novel ternary copper phosphides, A _2Cu _6P _5 (A = Sr, Eu) and EuCu _4P _3 [J] . Charkin D.O., Urmanov A.V., Kazakov S.M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第16期

机译：新型三元磷化铜A _2Cu _6P _5（A = Sr，Eu）和EuCu _4P _3的合成，晶体结构，输运和磁性
3. Copper Complexes with N-Allylisoquinolinium Halides: Synthesis and Crystal Structures of [C9H7N(C3H5)]2Cu~(II)Cl_(2.86)Br_(1.14), [C6H7N(C2H5)Cu~~IBr2] · H2O, and [C9H7N(C3H5)Cu~IBr2] [J] . A. V. Pavlyuk, V. V. Kinzhibalo, T. Lis Russian Journal of Coordination Chemistry . 2007,第7期

机译：N-烯丙基异喹啉鎓卤化物的铜配合物：[C9H7N（C3H5）] 2Cu〜（II）Cl_（2.86）Br_（1.14），[C6H7N（C2H5）Cu ~~ IBr2]·H2O和[C9H7N（ C3H5）Cu〜IBr2]
4. Synthesis, Single Crystal Structure, and Magnetic Properties of 3-D Cu(NITpPy)2Cu(CN)3.2CH3OH.2H2O Complexes [C] . I W Dasna, S Golhen, L Ouahab International Conference on Advanced Materials Science and Technology . 2017

机译：3-D Cu（Nitppy）2 Cu（CN）3 .2CH3OH2H2O复合物的合成，单晶结构和磁性性能
5. Structure-property relations in liquid crystalline and thermoplastic polymers: Crystal structure and morphology of liquid crystalline polyethers and the interaction of creep and physical aging in a semicrystalline thermoplastic matrix composite. [D] . Dean, Derrick Resha. 1994

机译：液晶和热塑性聚合物中的结构-性质关系：液晶聚醚的晶体结构和形态，以及半结晶热塑性基质复合材料中蠕变和物理老化的相互作用。
6. Various Structural Types of Cyanide-Bridged FeIII–MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis Crystal Structures and Magnetic Properties [O] . Wenlong Lan, Xiaoyun Hao, Yong Dou, 2019

机译：基于新的三氰基铁（III）构建基的氰化桥联的FeIII-MnIII双金属配位聚合物（CP）和多核簇的各种结构类型：合成晶体结构和磁性
7. Module-Based Assembly of Copper(II)-chloranilate Compounds: Synthesis, Crystal Structures and Magnetic Properties of {Cu2(CA)(terpy)2Cu(CA)2}n and {Cu2(CA)(terpy)2(dmso)2Cu(CA)2(dmso)2(EtOH)}n (H2CA = chloranilic acid, terpy = 22':6', 2'-t [O] . -1

机译：基于模块的铜（II）组装 - 氯氰酸盐化合物：{Cu2（Ca）（Terpy）2 Cu（Ca）2} N和{Cu2（Ca）（Terpy）的合成，晶体结构和磁性性质（Terpy ）2（DMSO）2 Cu（Ca）2（DMSO）2（EtOH）} N（H 2 Cl =氯酸，Terpy = 22'：6'，2'-T
8. Nano-Structures via Diffusion Limited Crystallization from Solution Precursors:Synthesis and Properties [R] . Lange, F. F. 1995

机译：纳米结构通过扩散有限结晶从溶液前体：合成和性质

Synthesis, crystal structure and properties of Li _2Cu _5(PO _4) _4

摘要

著录项

相似文献

相关主题

期刊订阅