Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl3(THF)(3)

Nachtigall Olaf; Pataki Astrid; Molski Matthias; Lentz Dieter; Spandl Johann

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Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl3(THF)(3)

机译：再谈三氯化锰的溶剂化物-MnCl3（THF）（3）的合成，分离和晶体结构

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The syntheses and crystal structures of [MnCl3(H2O)(THF)(2)]center dot 2THF (I), [MnCl4(THF)(2)][H(THF)(2)] (II), and [MnCl3(THF)(3)] (III) are reported. This study shows that former assumptions about the preparation of anhydrous MnCl3 and its etherates, published in the 1960s and earlier, have to be questioned. Instead of the conventional manganese sources, MnF3 was successfully utilized as starting material in THF to give water-free MnCl3 etherates. These findings are vital for further reactions where reactive but anhydrous MnCl3 derivatives are needed.

机译：[MnCl3（H2O）（THF）（2）]中心点2THF（I），[MnCl4（THF）（2）] [H（THF）（2）]（II）和[MnCl3的合成和晶体结构报告了（（THF）（3）]（III）。这项研究表明，必须质疑1960年代及更早出版的有关制备无水MnCl3及其醚化物的以前的假设。代替常规锰源，已成功地将MnF3用作THF中的起始原料，得到无水MnCl3醚化物。这些发现对于需要反应性但无水MnCl3衍生物的进一步反应至关重要。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2015年第6期|共5页
作者
Nachtigall Olaf; Pataki Astrid; Molski Matthias; Lentz Dieter; Spandl Johann;
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正文语种 eng
中图分类化学;
关键词
Manganese(III) halides; Manganese; Crystal structure;

机译：卤化锰;锰;晶体结构;

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Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl3(THF)(3)

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