Electron-rich, Nitrido-bridged Ruthenium Complexes

Glueer Arne; Askevold Bjorn; Schluschass Bastian; Heinemann Frank W.; Schneider Sven

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Electron-rich, Nitrido-bridged Ruthenium Complexes

机译：富电子，氮化桥式钌络合物

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Terminal Ru-IV nitride [RuN{N(CH2CH2PtBu2)(2)}] (1) and [RuCl{N(CH2CH2PtBu2)(2)}] (2a) form an equilibrium with bridging nitride [{(tBu(2)PCH(2)CH(2))(2)N} Ru(mu-N) RuCl{N(CH2CH2PtBu2)(2)}] (3a). While 3a could only be spectroscopically characterized yet not isolated, the reaction of the divinylamido chloro complex [RuCl{N(CHCHPtBu2)(2)}] (2b) with half an equivalent azide directly gave the analogous bridging nitride [{(tBu(2)PCHCH)(2)N} Ru(mu N) RuCl{N(CHCHPtBu2)(2)}] (3b), which was isolated and fully characterized.

机译：末端Ru-IV氮化物[RuN {N（CH2CH2PtBu2）（2）}]（1）和[RuCl {N（CH2CH2PtBu2）（2）}]（2a）与桥连氮化物[{（tBu（2）PCH （2）CH（2））（2）N} Ru（mu-N）RuCl {N（CH2CH2PtBu2）（2）}]（3a）。虽然3a只能通过光谱表征而不是分离，但是二乙烯基酰胺基氯络合物[RuCl {N（CHCHPtBu2）（2）}]（2b）与一半当量叠氮化物的反应直接产生了类似的桥连氮化物[{（tBu（2 ）PCHCH）（2）N} Ru（mu N）RuCl {N（CHCHPtBu2）（2）}]（3b），已分离并充分表征。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2015年第1期|共3页
作者
Glueer Arne; Askevold Bjorn; Schluschass Bastian; Heinemann Frank W.; Schneider Sven;
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正文语种 eng
中图分类化学;
关键词
Nitride; Ruthenium; Bridging ligands; Pincer ligand;

机译：氮化物;钌;桥接配体;针状配体;

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1. Electron-rich, Nitrido-bridged Ruthenium Complexes [J] . Glueer Arne, Askevold Bjorn, Schluschass Bastian, Zeitschrift fur Anorganische und Allgemeine Chemie . 2015,第1期

机译：富电子，氮化桥式钌络合物
2. Reactions of Ruthenium Complexes Having Pyridyl-Containing Ligands, 2-Pyridinecarboxylato and 2,2 '-Bipyridine, with an Azide Ion: Formation of Nitrido-Bridged Diruthenium Complexes [J] . Matsumura S, Shikano K, Oi T, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第20期

机译：具有含吡啶基的配体，2-吡啶基羧基和2,2'-联吡啶的钌配合物与叠氮化物离子的反应：硝化桥连二钌配合物的形成
3. A Nitrido-bridged Heterometallic Ruthenium(IV)/Iron(IV) Phthalocyanine Complex Supported by A Tripodal Oxygen Ligand, [Co(eta(5)-C5H5){P(O)(OEt)(2)}(3)](-): Synthesis, Structure, and Its Oxidation to Give Phthalocyanine Cation Radical and Hydroxyphthalocyanine Complexes [J] . Cheung Wai-Man, Ng Wai-Ming, Wong Wai-Ho, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第15期

机译：由三码氧氧配体负载的硝基桥桥杂核钌（IV）/铁（IV）酞菁络合物，[CO（ETA（5）-C5H5）{P（O）（OET）（2）}（3）]（ - ）：合成，结构及其氧化，得到酞菁阳离子的基团和羟基酞菁络合物
4. Computer Simulation of Ruthenium Complexes Molecules Density Functional Theory Study of Ruthenium Tris Chelate Complexes [C] . Wei Su, Jianguo Cui, Nana Guo, IEEE international conference on computer science and information technology . 2011

机译：钌三螯合物的分子密度泛函理论研究。
5. Photochemistry of group 8 metal complexes of type [M(bpy)2 cyanogen] (M = iron, ruthenium). Photosynthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) compounds, or, Photoassisted synthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) complexes. [D] . Turner, David Benjamin. 2009

机译：[M（bpy）2氰基]类型的第8组金属配合物的光化学（M =铁，钌）。杂合铁（II）化合物的光合作用和钌（II）化合物的光电离，或者杂合铁（II）化合物的光辅助合成和钌（II）配合物的光电离。
6. Editorial of Special Issue Ruthenium Complex: The Expanding Chemistry of the Ruthenium Complexes [O] . Ileana Dragutan, Valerian Dragutan, Albert Demonceau 2015

机译：特刊钌络合物的社论：钌络合物的扩展化学
7. Properties and reactivity of μ-nitrido-bridged dimetal porphyrinoid complexes: how does ruthenium compare to iron? [O] . M. Qadri E. Mubarak, Alexander B. Sorokin, Sam P. de Visser 2019

机译：μ-硝基桥桥二甲卟啉骨骨综合体的性质和反应性：钌与铁有何比较？
8. Chemically Significant Interactions Between Ruthenium Ions in Oxo-Bridged Complexes of Ruthenium(III). [R] . Weaver, T. R., Meyer, T. J., Adeyemi, A., 1974

机译：钌（III）羰基桥联配合物中钌离子之间的化学显着相互作用。

Electron-rich, Nitrido-bridged Ruthenium Complexes

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