Synthesis, Properties, and Crystal Structure of Cu_3Mo_8O_(23)X_2 (X = Cl, Br, I)

U. Steiner; W. Reichelt; P. Bottcher; S. Dabritz

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Synthesis, Properties, and Crystal Structure of Cu_3Mo_8O_(23)X_2 (X = Cl, Br, I)

机译：Cu_3Mo_8O_（23）X_2（X = Cl，Br，I）的合成，性质和晶体结构

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Single crystals of the Cu_3Mo_8O_(23)X_2 compounds were grown by chemical transport reactions at the lower temperature of a gradient 873-823 K without extra transport agent (auto transport). As DTA/TG measurements indicate, the gaseous compounds, necessary for chemical transport reactions, are formed by partial decomposition of Cu_3Mo_8O_(23)X_2 at 873 K. Cu_3Mo_8O_(23)Br_2 crystallizes with the orthouombic space group Pbcm (a = 4.021(1), b = 22.978(2), c = 21.673(2) A, Z = 4). The crystal structure consists of pentagonal columns _infinity~1[Mo_6O_7O_(20/2)] linked by additional MoO_(6/2) octahedra. All the polyhedra(pentagonal bipyramide, octahedra) are distorted. Infinite chains _infinty~1[Cu_3Br_2] along [100] are arranged in tunnels with s-like square shape, left open by the pentagonal columns. Cu_3Mo_8O_(23)Cl_2 (a = 4.010(1), b = 22.942(2), c = 21.639(2) A) and Cu_3Mo_8O_(23)I_2 (a = 4.052(1), b = 23.075(2), c = 21.719(2) A) are isotypic.

机译：Cu_3Mo_8O_（23）X_2化合物的单晶通过化学转运反应在873-823 K的较低温度下通过化学转运反应生长，无需额外的转运剂（自动转运）。正如DTA / TG测量所表明的那样，化学传递反应所需的气态化合物是通过在873 K处Cu_3Mo_8O_（23）X_2的部分分解而形成的.Cu_3Mo_8O_（23）Br_2以正交空间群Pbcm（a = 4.021（1 ），b = 22.978（2），c = 21.673（2）A，Z = 4）。晶体结构由五角形列_infinity〜1 [Mo_6O_7O_（20/2）]与附加的MoO_（6/2）八面体链接。所有的多面体（五角联吡啶，八面体）都变形了。沿[100]的无限链_infinty〜1 [Cu_3Br_2]排列成s形正方形的隧道，被五边形的圆柱敞开。 Cu_3Mo_8O_（23）Cl_2（a = 4.010（1），b = 22.942（2），c = 21.639（2）A）和Cu_3Mo_8O_（23）I_2（a = 4.052（1），b = 23.075（2），c = 21.719（2）A）是同型的。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1999年第1期|共7页
作者
U. Steiner; W. Reichelt; P. Bottcher; S. Dabritz;
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中图分类化学;
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copper molydenum oxide halide; chemical transport; crystal structure;

机译：铜氧化钼卤化物;化学输运;晶体结构;

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Synthesis, Properties, and Crystal Structure of Cu_3Mo_8O_(23)X_2 (X = Cl, Br, I)

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