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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Au(Et(2)dtc)(2)][TcNCl4] - Synthesis and structure [German
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Au(Et(2)dtc)(2)][TcNCl4] - Synthesis and structure [German

机译:Au(Et(2)dtc)(2)] [TcNCl4]-合成与结构[德语]

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摘要

Au(Et(2)dtc)(2)][TcNCl4] (Et(2)dtc(-) = N,N-diethyldithiocarbamate) is formed by the reaction of [Au(CO)CI] with [TcN(Et(2)dtc)(2)] in dichloromethane, The solid state structure of the compound is characterized by a large triclinic unit cell (space group, P (1) over bar, a = 9.422(2), b = 22.594(5), c = 32.153(7) Angstrom, alpha = 72.64(1), beta = 85.19(1), gamma = 86.15(1)degrees, Z = 12) and shows an unusual arrangement due to long-range contacts between the technetium atoms and sulfur atoms of the [Au(Et(2)dtc)(2)](+) units (3.45-3.56 Angstrom) which assemble two anions and one cation to {[TcNCl4][Au(Et(2)dtc)(2)].[TcNCl4]}(-) moieties. [References: 17
机译:Au [Et(2)dtc)(2)] [TcNCl4](Et(2)dtc(-)= N,N-二乙基二硫代氨基甲酸酯)是通过[Au(CO)Cl]与[TcN(Et( 2)dtc)(2)]在二氯甲烷中,该化合物的固态结构的特征是具有较大的三斜晶系​​晶胞(空间群,P(1)超过bar,a = 9.422(2),b = 22.594(5) ,c = 32.153(7)埃,alpha = 72.64(1),beta = 85.19(1),γ= 86.15(1)度,Z = 12),并且由于the原子之间的长距离接触而显示出不寻常的排列和[Au(Et(2)dtc)(2)](+)单元(3.45-3.56埃)的硫原子,它们将两个阴离子和一个阳离子组装到{[TcNCl4] [Au(Et(2)dtc)( 2)]。[TcNCl4]}(-)部分。 [参考:17

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