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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Contributions to the chemistry of silicon-sulfur compounds. 72 - Synthesis and structural studies of new (triphenylphosphine) (trialkoxysilanethiolato)gold(I) complexes
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Contributions to the chemistry of silicon-sulfur compounds. 72 - Synthesis and structural studies of new (triphenylphosphine) (trialkoxysilanethiolato)gold(I) complexes

机译:对硅硫化合物化学的贡献。 72-新的(三苯基膦)(三烷氧基硅烷硫基)金(I)配合物的合成和结构研究

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Compounds of general formula Au{SSi(OR)(3)}(PPh3), R = Pr-i (1), Bu-s (2) or Bu-t (3), have been obtained by reaction of AuCl(PPh3) with triethylammonium salts of respective silanethiols, (RO)(3)SiSH. Molecular and crystal structures of 1, 2, and 3 have been determined by the single crystal X-ray structural analysis. Compounds 1 and 2 are the first structurally characterized metal derivatives of hydrolytically unstable trialkoxysilanethiols (Pr(i)0)(3)SiSH and ((BuO)-O-5)(3)SiSH. first structurally characterized metal derivatives of hydrolytically unstable trialkoxysilanethiols ((PrO)-O-i)(3)SiSH and ((BuO)-O-s)(3) SiSH. [References: 26]
机译:通过AuCl(PPh3)的反应获得了通式为Au {SSi(OR)(3)}(PPh3),R = Pr-i(1),Bu-s(2)或Bu-t(3)的化合物)与各自的硅烷硫醇的三乙基铵盐(RO)(3)SiSH。通过单晶X射线结构分析已经确定了1、2和3的分子和晶体结构。化合物1和2是水解不稳定的三烷氧基硅烷硫醇(Pr(i)0)(3)SiSH和((BuO)-O-5)(3)SiSH的第一个结构表征的金属衍生物。水解不稳定的三烷氧基硅烷硫醇((PrO)-O-i)(3)SiSH和((BuO)-O-s)(3)SiSH的第一结构特征金属衍生物。 [参考:26]

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