Metal salts of benzene-1,2-di(sulfonyl)amine. 8. Lamellar layers based upon hydrogen bonding and pi-stacking: Crystal structures of the complexes [Mg(H2O)(6)]Z(2) and [Be(H2O)(4)]Z(2)center dot 2 H2O, where Z(-) is C6H4(SO2)(2)N- [German]

Moers O.; Friedrichs S.; Blaschette A.; Jones PG.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Metal salts of benzene-1,2-di(sulfonyl)amine. 8. Lamellar layers based upon hydrogen bonding and pi-stacking: Crystal structures of the complexes [Mg(H2O)(6)]Z(2) and [Be(H2O)(4)]Z(2)center dot 2 H2O, where Z(-) is C6H4(SO2)(2)N- [German]

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Metal salts of benzene-1,2-di(sulfonyl)amine. 8. Lamellar layers based upon hydrogen bonding and pi-stacking: Crystal structures of the complexes [Mg(H2O)(6)]Z(2) and [Be(H2O)(4)]Z(2)center dot 2 H2O, where Z(-) is C6H4(SO2)(2)N- [German]

机译：苯1,2-二（磺酰基）胺的金属盐。 8.基于氢键和π堆积的层状层：[Mg（H2O）（6）] Z（2）和[Be（H2O）（4）] Z（2）中心点2 H2O的晶体结构，其中Z（-）为C6H4（SO2）（2）N- [德语]

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The crystal structures of the title complexes (both triclinic, space group P1, Z = 1 for M = Mg, Z = 2 for M = Be) have been determined by low-temperature X-ray diffraction. They consist of non-coordinating ortho-benzenedisulfonimide anions and, respectively, inversion-symmetric octahedral [Mg(H2O)(6)](2+) cations or tetrahedral [Be(H2O)(4)](2+) cations and two non-coordinating water molecules. In both structures, all O-H hydrogen bond donor groups are used to associate the components into two-dimensional assemblies comprising an internal polar lamella of metal cations, (SO2)(2)N groups and water molecules, and hydrophobic peripheral regions consisting of vertically protruding benzo rings. Carbocycles drawn alternatingly from adjacent layers form pi-stacking arrays, whereby the aromatic rings display intercentroid distances in the range 340-370 pm. Several short C-H...O contacts, which may be viewed as weak hydrogen bonds, occur within and between the layers. [References: 24]

机译：标题配合物的晶体结构（均为三斜晶系，空间群P1，M = Mg为Z = 1，M = Be为Z = 2）已通过低温X射线衍射确定。它们分别由非配位的邻苯二磺酰亚胺阴离子和反相对称的八面体[Mg（H2O）（6）]（2+）阳离子或四面体[Be（H2O）（4）]（2+）阳离子和两个非配位水分子。在这两种结构中，所有OH氢键供体基团均用于将组分关联为二维组件，包括金属阳离子的内部极性薄片，（SO2）（2）N基团和水分子以及由垂直突出组成的疏水性外围区域苯并环。从相邻层交替抽取的碳轮形成pi堆积阵列，其中芳环显示的质心间距在340-370 pm之间。在层内和层之间会发生几个短的C-H ... O接触，这些接触可能被视为弱氢键。 [参考：24]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2002年第3期|共7页
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Moers O.; Friedrichs S.; Blaschette A.; Jones PG.;
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1. Metal salts of benzene-1,2-di(sulfonyl)amine. 8. Lamellar layers based upon hydrogen bonding and pi-stacking: Crystal structures of the complexes [Mg(H2O)(6)]Z(2) and [Be(H2O)(4)]Z(2)center dot 2 H2O, where Z(-) is C6H4(SO2)(2)N- [German] [J] . Moers O., Friedrichs S., Blaschette A., Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第3期

机译：苯1,2-二（磺酰基）胺的金属盐。 8.基于氢键和π堆积的层状层：[Mg（H2O）（6）] Z（2）和[Be（H2O）（4）] Z（2）中心点2 H2O的晶体结构，其中Z（-）为C6H4（SO2）（2）N- [德语]
2. Metal salts of benzene-1,2-di(sulfonyl)amine. 6. A lamellar layer network based upon hydrogen bonding and pi-stacking: Crystal structure of the lithium complex [Li{C6H4(SO2)(2)N}(H2O)3], and a comparative survey of metal(I) benzene-1,2-di(sulfonyl)am [J] . Moers O., Blaschette A., Jones PG. Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第2期

机译：苯1,2-二（磺酰基）胺的金属盐。 6.基于氢键和π堆积的层状层网络：锂络合物[Li {C6H4（SO2）（2）N}（H2O）3]的晶体结构，以及金属（I）苯的比较调查1,2-二（磺酰基）am
3. Metal salts of benzene-1,2-di(sulfonyl)amine. 4. Hydrophobically wrapped two-dimensional polymers: Crystal structures of the isostructural metal complexes [M{C6H4(SO2)(2)N}(H2O)] (M = K, Rb) and of the structurally related ammonium salt [(NH4){C6H4(S [J] . Moers O., Blaschette A., Jones PG., Zeitschrift fur Anorganische und Allgemeine Chemie . 2001,第11期

机译：苯1,2-二（磺酰基）胺的金属盐。 4.疏水包裹的二维聚合物：等结构金属配合物[M {C6H4（SO2）（2）N}（H2O）]（M = K，Rb）和与结构相关的铵盐[（NH4）的晶体结构{C6H4（S
4. A Novel Hybrid Compound Based on Polyoxometalate, Synthesis and Crystal Structure ofSm(NMP)4(H2O)4 HSiMo12O40·2NMP·H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：Sm（NMP）4（H2O）4 HSiMo12O40·2NMP·H2O的多金属氧酸酯杂化化合物，合成及晶体结构
5. New phases in the hydrous ferric sulfate system, a supporting argument that the mineral lausenite is of formula Fe2(SO4 )3·5H2O and the crystal structure refinement and hydrogen bonding scheme of the minerals quenstedtite and romerite [D] . Westland, Robin Elizabeth 2012

机译：含水硫酸铁体系中的新相，支持的论据是，矿物绿铁矿的分子式为Fe2（SO4）3·5H2O，以及芒硝和硅镁矿矿物的晶体结构细化和氢键合方案
6. Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na2(3-chlorobenzoate)212-MCMn(III)N(shi)-4(DMF)6 and MnNa(3-chlorobenzoate)312-MCMn(III)N(shi)-4(DMF)(H2O)4·4DMF·0.72H2O [O] . Curtis M. Zaleski, Matthias Zeller 2020

机译：两种锰基12-金属镧4配合物的合成和晶体结构：Na2（3-氯苯甲酸酯）2 12-MCMn（III）N（shi）-4（DMF）6和MnNa（3-氯苯甲酸酯）3 12-MCMn（III）N（shi）-4（DMF）（H2O）4·4DMF·0.72H2O
7. Synthesis and Anti-Candida Activity of Cobalt(II) Complexes of Benzene-1,2-Dioxyacetic Acid (bdoaH2). X-Ray Crystal Structures of [Co(bdoa)(H2O)3] ⋅3.5H2O and {[CO(phen)3](bdoa)}2⋅24H2O (phen = 1,10-Phenanthroline) [O] . Geraghty, Majella, McCann, Malachy, Devereux, Michael, 1999

机译：钴（II）配合物的合成及其抗念珠菌活性。苯1,2-二氧乙酸（bdoaH2）。 [Co（bdoa）（H2O）3]的X射线晶体结构 ⋅3.5H2O和{[CO（phen）3]（bdoa）}2⋅24H2O （phen = 1,10-菲咯啉）

Metal salts of benzene-1,2-di(sulfonyl)amine. 8. Lamellar layers based upon hydrogen bonding and pi-stacking: Crystal structures of the complexes [Mg(H2O)(6)]Z(2) and [Be(H2O)(4)]Z(2)center dot 2 H2O, where Z(-) is C6H4(SO2)(2)N- [German]

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