Mononuclear complexes of copper(I), palladium(II), and ruthenium(II) with oxalic amidine-type ligands by coupled cation-/anion coordination [German]

Bottcher L.; Scholz A.; Walther D.; Weisbach N.; Gorls H.

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Mononuclear complexes of copper(I), palladium(II), and ruthenium(II) with oxalic amidine-type ligands by coupled cation-/anion coordination [German]

机译：铜（I），钯（II）和钌（II）与草酸am型配体的单核配合物，通过阳离子/阴离子配位[德国]

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Oxalamidines (RN)-N-1=C(NHR2)-C(=NHR2) =NR1 (H(2)A: R-1 = R-2 = p-tolyl; H2B: R-1 = R-2 = mesityl) react with [Cu(CH3CN)(4)(BF4)/PPh3 to form the mononuclear complexes {[(Ph3P)(2)Cu]AH(2)(F4B)} (1) and {[(Ph3P)Cu]BH2(F4B)} (2). X-ray diffraction measurements of single crystals show that Cu-I is coordinated at the 1,4-diazadiene unit. Tetrafluoroborat is bonded at the 1,2-diamine unit via hydrogen bonds ("coupled cation-/anion coordination"). [(allyl)PdCl](2) reacts with H(2)A to form the allyl complex [(allyl)PdAH(2)...Cl-2(allyl)Pd] (3). With H2B the analogous compound 4 is formed. In these complexes the (allyl)Pd+-fragment is coordinated at the 1,4-diazadiene part of the neutral oxalic amidine ligand. In addition, [allylPdCl(2)](-) coordinates at the 1,2-diamine site. By analogous coupled cation-/anion coordination some Run complexes, e. g. [(p-cymolRu(Cl)CH2...Cl] (6), and [(4,4',4"-tri-t-butyl-terpyridin)(Cl)RuAH(2)...Cl] (9) can be prepared. [References: 32]

机译：草酰（（RN）-N-1 = C（NHR2）-C（= NHR2）= NR1（H（2）A：R-1 = R-2 =对甲苯基; H2B：R-1 = R-2 = mesityl）与[Cu（CH3CN）（4）（BF4）/ PPh3反应形成单核络合物{[（Ph3P）（2）Cu] AH（2）（F4B）}（1）和{[（Ph3P）Cu ] BH2（F4B）}（2）。单晶的X射线衍射测量表明，Cu-1在1，4-二氮杂二烯单元上是配位的。四氟硼酸酯通过氢键在1,2-二胺单元上键合（“阳离子/阴离子配位偶联”）。 [（烯丙基）PdCl]（2）与H（2）A反应形成烯丙基络合物[（烯丙基）PdAH（2）... Cl-2（烯丙基）Pd]（3）。用H 2 B形成类似的化合物4。在这些络合物中，（烯丙基）Pd +片段配位在中性草酸am配体的1,4-二氮杂二烯部分。此外，[allylPdCl（2）]（-）在1,2-二胺位点进行配位。通过类似的阳离子-阴离子配位，一些Run配合物，如G。 [（p-cymolRu（Cl）CH2 ... Cl]（6）和[（4,4'，4“-三叔丁基-萜啶）（Cl）RuAH（2）... Cl]（ 9）可以准备[参考文献：32]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2003年第13期|共10页
作者
Bottcher L.; Scholz A.; Walther D.; Weisbach N.; Gorls H.;
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正文语种 ger
中图分类化学;
关键词
Copper; Ruthenium; Palladium; Hydrogen bonds; Molecular-structure; Crystal-structures; 2; 2'-biimidazole; Dinuclear; Chloride; Triphenylphosphane; Oxalamidines; Biimidazole; Mossbauer;

机译：铜;钌;钯;氢键;分子结构;晶体结构;2;2'-联咪唑;双核;氯化物;三苯基膦;氧杂al啶;苯并咪唑;Mossbauer;

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1. Mononuclear complexes of copper(I), palladium(II), and ruthenium(II) with oxalic amidine-type ligands by coupled cation-/anion coordination [German] [J] . Bottcher L., Scholz A., Walther D., Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第12a13期

机译：铜（I），钯（II）和钌（II）与草酸am型配体的单核配合物，通过阳离子/阴离子配位[德国]
2. Coordination chemistry of mixed pyridine-phenol ligands; mononuclear palladium(II) and dinuclear copper(II) complexes of derivatives of bidentate N,O-chelating ligands based on 2-(2-hydroxyphenyl)pyridine [J] . Otter CA., Couchman SM., Jeffery JC., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第2a3期

机译：吡啶-酚混合配体的配位化学;基于2-（2-羟苯基）吡啶的二齿N，O螯合配体衍生物的单核钯（II）和双核铜（II）配合物
3. Metal complexes of biologically important ligands. CIII. Palladium(Il), platinum(II), ruthenium(II), rhodinum(III), and iridium(III) complexes of desoxyfructosazine [German] [J] . Krawielitzki S., Beck W. Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第10期

机译：具有生物学重要性的配体的金属配合物。 CIII。脱氧果糖嗪的钯（II），铂（II），钌（II），铑（III）和铱（III）配合物[德语]
4. Luminescence Properties of Organometallic/Coordination Oligomers and Polymers Containing Diphosphine and Diisocyanide Assembling Ligands: Comparison between Mononuclear Model Complexes and Polymers [C] . Pierre D. Harvey Macromolecular Symposia 209; Organometallic and Coordination Clusters and Polymers: Syntheses and Applications Symposium; 20040529-0601; London(CA) . 2004

机译：有机金属/配位低聚物和含二膦和二异氰酸酯组装配体的聚合物的发光性质：单核模型配合物和聚合物之间的比较。
5. The magnetism and coordination chemistry of mononuclear and polynuclear complexes of copper(II) and other first row transition metal ions derived from open-chain diazine (N-N) ligands. [D] . Xu, Zhiqiang. 1998

机译：铜（II）和其他来自开链二嗪（N-N）配体的第一行过渡金属离子的单核和多核配合物的磁性和配位化学。
6. Synthesis and Characterization of Cobalt(III) Nickel(II) and Copper(II) Mononuclear Complexes with the Ligand 13-bis(2-aminoethyl)amino-2-propanol and Their Catalase-Like Activity [O] . Bianca M. Pires, Daniel M. Silva, Lorenzo C. Visentin, -1

机译：13-双（2-氨基乙基）氨基 -2-丙醇配体钴（III）镍（II）和铜（II）单核配合物的合成表征及其过氧化氢酶样活性
7. Mononuclear to Polynuclear Transition Induced by Ligand Coordination: Synthesis, X-ray Structure, and Properties of Mono-, Di-, and Polynuclear Copper(II) Complexes of Pyridyl-Containing Azo Ligands [O] . -1

机译：通过配体配位诱导的多核转变为多核转变：合成，X射线结构和单核和多核铜（II）含吡啶唑类配体的络合物的性质
8. Studies of the Complexes Formed Between the 5-Trifluoromethyletetrazol Anion and Some Divalent Transition Metal Ions. Magnetochemical and Spectral Studies of Some Copper (II) Complexes of Substituted Benzoic Acids. Copper (II) Halide Complexes with Substituted Pyridine n-Oxides [R] . Harris, A. D., Jonassen, H. B., Mallory, T. L., 1964

机译：5-三氟甲基四唑阴离子与一些二价过渡金属离子形成的配合物的研究。一些取代苯甲酸铜（Ⅱ）配合物的磁化学和光谱研究。具有取代的吡啶n-氧化物的铜（II）卤化物配合物

Mononuclear complexes of copper(I), palladium(II), and ruthenium(II) with oxalic amidine-type ligands by coupled cation-/anion coordination [German]

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