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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Hetero-metallic Lanthanide CPs Involving Sodium: Synthesis, Crystal Structure, and Luminescence Properties
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Hetero-metallic Lanthanide CPs Involving Sodium: Synthesis, Crystal Structure, and Luminescence Properties

机译:涉及钠的杂金属镧系元素CP:合成,晶体结构和发光性能

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摘要

[TbNa(4-msal)_4(phen)_2]_n (1) (4-msal = 4-methyl salicylic acid), a new hetero-metallic lanthanide coordination polymer (CP) involving sodium was synthesized. It crystallizes in the monoclinic space group P2_1, with a = 20.4809(9) ?, b = 9.8183(2) ?, c = 26.1987(11) ?, α = 90.00°, β = 112.922(5)°, γ = 90.00°, V = 4852.2(3) ?~3, and Z = 4. The complex was characterized by single crystal and powder X-ray diffraction, elemental analysis (EA), and Fourier transform infrared (FT-IR) and luminescence spectroscopy. The luminescence properties of a powder sample of 1 were studied at room temperature and the luminescence lifetime and total quantum yield (QY) were determined.
机译:[TbNa(4-msal)_4(phen)_2] _n(1)(4-msal = 4-甲基水杨酸),是一种新的涉及钠的杂金属镧系配位聚合物(CP)。它在单斜空间群P2_1 / n中结晶,a = 20.4809(9)α,b = 9.8183(2)α,c = 26.1987(11)α,α= 90.00°,β= 112.922(5)°,γ = 90.00°,V = 4852.2(3)α〜3,Z =4。该配合物的特征在于单晶和粉末X射线衍射,元素分析(EA),傅立叶变换红外(FT-IR)和发光光谱学。在室温下研究粉末样品1的发光特性,并确定其发光寿命和总量子产率(QY)。

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