A New Manganese(II) Coordination Polymer based on 1H-benzimidazole-5-carboxylic Acid:Synthesis, Structure, and Magnetic Property

Xia Li; Jing Li; Ming-Kai Li; Zhou Fei

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A New Manganese(II) Coordination Polymer based on 1H-benzimidazole-5-carboxylic Acid:Synthesis, Structure, and Magnetic Property

机译：基于1H-苯并咪唑-5-羧酸的新型锰（II）配位聚合物：合成，结构和磁性

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A new Mn~(II) coordination polymer, namely [Mn_3(Hbic)_6]_n (1) (H_2bic = 1H-benzimidazole-5-carboxylic acid), was obtained through the hydrothermal reaction of MnCl_2 and H_2bic. Single crystal X-ray analysis reveals that compound 1 exhibits a 2D layer structure with 4-connected sql topology by viewing trinuclear [Mn_3(COO)_6] subunits as nodes and Hbic ligands as linkers, and further packing of these 2D sheets by intermolecular hydrogen bonds leads to a 3D supramolecular framework. Variable-temperature magnetic susceptibility measurements reveal that there exists antiferromagnetic interaction between the Mn~(II) ions.

机译：通过MnCl_2与H_2bic的水热反应，得到了一种新的Mn〜（II）配位聚合物，即[Mn_3（Hbic）_6] _n（1）（H_2bic = 1H-苯并咪唑-5-羧酸）。单晶X射线分析表明，化合物1通过以三核[Mn_3（COO）_6]亚基为节点，以Hbic配体为连接基，并通过分子间氢进一步填充这些2D片，从而显示具有4个连接的sql拓扑的2D层结构。键导致3D超分子框架。可变温度磁化率测量表明，Mn〜（II）离子之间存在反铁磁相互作用。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第7期|共5页
作者
Xia Li; Jing Li; Ming-Kai Li; Zhou Fei;
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正文语种 eng
中图分类化学;
关键词
Manganese; Polymers; Hydrothermal reaction; Trinuclear cluster; Topology; Magnetic property;

机译：锰;聚合物;水热反应;三核团簇;拓扑;磁性;

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1. A New Manganese(II) Coordination Polymer based on 1H-benzimidazole-5-carboxylic Acid:Synthesis, Structure, and Magnetic Property [J] . Xia Li, Jing Li, Ming-Kai Li, Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第7期

机译：基于1H-苯并咪唑-5-羧酸的新型锰（II）配位聚合物：合成，结构和磁性
2. Synthesis, crystal structures, and magnetic properties of 2D manganese(II) and 1D gadolinium(III) coordination polymers with 1H-1,2,3-triazole-4,5-dicarboxylic acid [J] . Shi W, Chen XY, Xu N, European journal of inorganic chemistry . 2006,第23期

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机译：无机配位聚合物。第十九部分。烃侧基的立体效应对锌（II），钴（II），锰（II），镍（II）和铜（II）双（次膦酸盐）的结构和性质的影响。

A New Manganese(II) Coordination Polymer based on 1H-benzimidazole-5-carboxylic Acid:Synthesis, Structure, and Magnetic Property

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