Reactions of Potassium Iodomercurate(II) with Crown Ethers and Cryptands: Crystal Structures of Bis[di(benzo-15-crown-5)potassium]-, Di[benzo-18-crown-6)potassium]-, Di[(cryptand 221)potassium]-, and Di[(cryptand 222)potassium] Hexaiododimercurate(II

J. Pickardt; P. Wischlinski

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Reactions of Potassium Iodomercurate(II) with Crown Ethers and Cryptands: Crystal Structures of Bis[di(benzo-15-crown-5)potassium]-, Di[benzo-18-crown-6)potassium]-, Di[(cryptand 221)potassium]-, and Di[(cryptand 222)potassium] Hexaiododimercurate(II

机译：碘化高碘酸钾（II）与冠醚和土醚的反应：双[二（苯并-15-冠-5）钾]-，双[苯并-18-冠-6]钾]-，二[（隐窝）的晶体结构221）钾]-和二[（土和222）钾]六碘二汞（II

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The reactions of potassium iodomercurate(II) with the crown ethers benzo-15-crown-5, and benzo-18-crown-6, resp. as well as with the cryptands 221 and 222 were investigated. In all cases only the potassium ion was complexed. As anions only hexaiododimercurate(II) ions were formed but no higher oligomers. If the complexed potassium ion is not completely shielded by the ligand, further coordination by terminal iodine atoms of the mercurate anions takes place, leading to the formation of dimers or chains.

机译：碘化氢钾（II）与冠醚苯并15-15-冠5和苯并18-冠6的反应。以及与配体221和222一起进行了研究。在所有情况下，仅钾离子是络合的。作为阴离子，仅形成六碘二汞（II）离子，而没有更高的低聚物。如果配位的钾离子没有被配体完全屏蔽，则汞离子阴离子的末端碘原子会进一步配位，从而导致二聚体或链的形成。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1999年第9期|共5页
作者
J. Pickardt; P. Wischlinski;
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正文语种 ger
中图分类化学;
关键词
crown compounds; cryptands; iodomercurates; crystal structure;

机译：冠状化合物;穴状配体;碘酸盐;晶体结构;

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1. Reactions of Potassium Iodomercurate(II) with Crown Ethers and Cryptands: Crystal Structures of Bis[di(benzo-15-crown-5)potassium]-, Di[benzo-18-crown-6)potassium]-, Di[(cryptand 221)potassium]-, and Di[(cryptand 222)potassium] Hexaiododimercurate(II [J] . J. Pickardt, P. Wischlinski Zeitschrift fur Anorganische und Allgemeine Chemie . 1999,第9期

机译：碘化高碘酸钾（II）与冠醚和土醚的反应：双[二（苯并-15-冠-5）钾]-，双[苯并-18-冠-6]钾]-，二[（隐窝）的晶体结构221）钾]-和二[（土和222）钾]六碘二汞（II
2. A moderate distortion of the `picket-fence' porphyrin (cryptand-222)potassium chlorido[meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinato]ferrate(II) n-hexane monosolvate [J] . Yu Qiang, Liu Diansheng, Li Xiangjun, Acta crystallographica. Section C, Structural chemistry. . 2015,第10期

机译：栅栏型卟啉（cryptand-222）氯化钾[间位-α，α，α，α-四（邻-新戊酰胺基苯基）卟啉对]高铁酸盐（II）正己烷单溶剂的适度变形
3. A moderate distortion of the 'picket-fence' porphyrin (cryptand-222) potassium chlorido[meso-alpha,alpha,alpha, alpha-tetrakis(o-pivalamidophenyl)-porphyrinato]ferrate(II) n-hexane monosolvate [J] . Yu Qiang, Liu Diansheng, Li Xiangjun, Acta crystallographica. Section F, Structural biology communications . 2015,第10期

机译：“拾栅围栏”卟啉（Cryptand-222）氯通钾[Meso-alpha，α，α，α-四（戊酰胺苯基苯基苯基）-卟啉（II）N-己烷单溶化物的抗变形
4. Synthesis and Crystal Structure of a Stable Bimetallic Neodymium (III)-Potassium Complex with the O-Benzenedisulfonate Ligand [C] . G.B.Deacon, A.Gitlits International Conference on Rare Earths . 1999

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机译：双水5101520-四（4-甲基氧苯基）基卟啉-κ4的晶体结构N铁（III）二水合（18冠6）双（三氟甲烷磺酸盐）钾–18冠6（1/2）
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Reactions of Potassium Iodomercurate(II) with Crown Ethers and Cryptands: Crystal Structures of Bis[di(benzo-15-crown-5)potassium]-, Di[benzo-18-crown-6)potassium]-, Di[(cryptand 221)potassium]-, and Di[(cryptand 222)potassium] Hexaiododimercurate(II

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