Synthesis, structural characterization and luminescent properties of a mixed valence hexavanadate cluster

Zhang GL; Li YT; Luo XQ; Wu ZY

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis, structural characterization and luminescent properties of a mixed valence hexavanadate cluster

【24h】

Synthesis, structural characterization and luminescent properties of a mixed valence hexavanadate cluster

机译：混合价六钒酸盐簇的合成，结构表征和发光性质

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

An inorganic-organic vanadate compound [V(6)o(12)(OCH3)(4)(dmbPY)(4)center dot H2O] (dmbpy = 4,4'-dimethyl-2,2'-bipyridine) has been synthesized and characterized by elemental analyses, IR, UV spectra and single crystal X-ray diffraction. The compound crystallizes in monoclinic system, space group P2(1) (No. 14), a = 11.317(2) angstrom, b = 18.557(3) angstrom, c = 14.630(3) angstrom, beta = 101.58(4)degrees, V = 3012.5(9) angstrom(3), and Z = 2. The crystal structure consists of a new hexavanadate cluster and four dmbpy groups which directly coordinated to vanadium through nitrogen atoms. The hydrogen bonds contribute to the formation of the three-dimensional supramolecular structure. Fluorescent analyses show that it exhibits intense blue photoluminescence in DMF solution at room temperature.

机译：无机-有机钒酸盐化合物[V（6）o（12）（OCH3）（4）（dmbPY）（4）中心点H2O]（dmbpy = 4,4'-二甲基-2,2'-联吡啶）通过元素分析，红外，紫外光谱和单晶X射线衍射合成和表征。该化合物在单斜晶系统，空间群P2（1）/ n（第14号），a = 11.317（2）埃，b = 18.557（3）埃，c = 14.630（3）埃，β= 101.58（4）中结晶）度，V = 3012.5（9）埃（3），Z =2。晶体结构由一个新的六钒酸盐簇和四个dmbpy基组成，它们通过氮原子直接与钒配位。氢键有助于三维超分子结构的形成。荧光分析表明，在室温下，它在DMF溶液中表现出强烈的蓝色光致发光。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2008年第7期|共5页
作者
Zhang GL; Li YT; Luo XQ; Wu ZY;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
vanadium; dimethyldipyridine; luminescent properties; LAYERED VANADIUM-OXIDE; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; COMPLEXES; POLYOXOVANADATE; CHEMISTRY; BATTERIES; H2O;

机译：钒;二甲基二吡啶;发光性能;层状氧化钒;水热合成;晶体结构;分子结构;络合物;聚氧钒酸盐;化学性质;电池;H2O;

相似文献

外文文献
中文文献
专利

1. Synthesis, structural characterization and luminescent properties of a mixed valence hexavanadate cluster [J] . Zhang GL, Li YT, Luo XQ, Zeitschrift fur Anorganische und Allgemeine Chemie . 2008,第6a7期

机译：混合价六钒酸盐簇的合成，结构表征和发光性质
2. An unexpected mixed valence tetranuclear copper(I/II) complex: Synthesis, structural characterization, DNA/protein binding, antioxidant and anticancer properties [J] . Anu D., Naveen P., VijayaPandiyan B., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2019,第期

机译：意外的混合价四核铜（I / II）复合物：合成，结构表征，DNA /蛋白结合，抗氧化剂和抗癌性能
3. HYDROTHERMAL SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND PHYSICAL PROPERTIES OF A NEW MIXED VALENCE IRON PHOSPHATE, SrFe3(PO4)3 [J] . Korzenski MB, Long GJ, Kolis JW International Journal of Quantum Chemistry . 1999,第1期

机译：新型混合价磷酸铁SrFe3（PO4）3的水热合成，结构表征和物理性质
4. Electric Field Control of Magnetic and Polarizability Properties of Trimeric Mixed Valence Clusters [C] . M. Roman, O. Reu, S. Klokishner International Conference on Nanotechnologies and Biomedical Engineering . 2016

机译：三聚体混合价簇的磁性和极化性能的电场控制
5. Macrocyclic chemistry: Part I. Synthesis, characterization and alkali metal stability constants of a new bis(phosphotriester) macrobicyclic polyether cryptand; Part II. Characterization of a new valence-averaged mixed-valence di-ruthenium complex, and of an iron beta-diimine keto macrocyclic complex. [D] . Allan, Christian Bruce. 1994

机译：大环化学：第一部分。新型双（磷酸三酯）大双环聚醚穴状配体的合成，表征和碱金属稳定性常数；第二部分表征新的价平均混合价二钌配合物和铁β-二亚胺酮大环配合物。
6. Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex: {Bis(ethylenediamine) Copper (II) Bisdiiodocuprate (I)} [O] . Lida Fotouhi, Saeed Dehghanpour, Majid M. Heravi, 2007

机译：新型混合价铜（I）-铜（II）配合物的电化学合成和结构表征：{双（乙二胺）铜（II）双二碘多丁酸酯（I）}
7. Alkynyl-Phosphine Substituted Fe2S2 Clusters: Synthesis, Structure and Spectroelectrochemical Characterization of a Cluster with a Class III Mixed-Valence FeFe3+ Core [O] . Gregory L. Newman, Jamil M. A. Rahman, Josef B. G. Gluyas, 2014

机译：炔基次取代的Fe2S2簇：簇的合成，结构和光谱电化学表征与III类混合价π3+芯的簇
8. Metal Atom Synthesis of Metallaboron Clusters. 8. Synthesis of New Cobalt, Iron, and Nickel Clusters Derived from 2,6-C2B7H11. Structural Characterization of 2-ETA 6-C6(CH3)3H3 Fe-1,6-C2B7H9, 6-ETA 6-C6(CH3)3H3 Fe-9,10-C2B7H11, an [R] . Sneddon, L. G., Briguglio, J. J. 1986

机译：metallaboron团簇的金属原子合成。 8.衍生自2,6-C2B7H11的新的钴，铁和镍簇的合成。 2-ETa 6-C6（CH3）3H3Fe-1,6-C2B7H9,6-ETa6-C6（CH3）3H3Fe-9,10-C2B7H11的结构表征

Synthesis, structural characterization and luminescent properties of a mixed valence hexavanadate cluster

摘要

著录项

相似文献

相关主题

期刊订阅