Synthesis, characterization, and crystal structure of the new Schiff-bases derived from 1,2,4-triazole and the structure of [(PPh3)(2)Cu(AMTT)NO3 center dot EtOH (AMTT=4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione)

Heshmatpour F; Ghassemzadeh M; Semsarha M; Neumuller B

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Synthesis, characterization, and crystal structure of the new Schiff-bases derived from 1,2,4-triazole and the structure of [(PPh3)(2)Cu(AMTT)NO3 center dot EtOH (AMTT=4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione)

机译：1,2,4-三唑衍生的新席夫碱的合成，表征和晶体结构以及[（PPh3）（2）Cu（AMTT）NO3中心点EtOH（AMTT = 4-amino-5-甲基-2H-1,2,4-三唑-3（4H）-硫酮）

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The reactions of 4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione (AMTT, L1) with 2-thiophen carbaldehyde, salicylaldehyde and 2-nitrobenzaldehyde in methanol led to the corresponding Schiff-bases (L1a-c). The reaction of L1 with [(PPh3)(2)Cu]NO3 in ethanol gave the ionic complex [(PPh3)(2)Cu(L1)](NO3EtOH)-Et-. (2) All compounds were characterized by infrared spectroscopy, elemental analyses as well as by X-ray diffraction studies. Crystal data for L1a at 20 degrees C: space group P2(1) with a 439.6(2), b = 2074.0(9), c = 1112.8(4) pm, beta = 93.51(3)degrees, Z = 4, R-1 = 0.0406, L1b at -80 degrees C: space group P2(1) with a = 1268.9(2), b = 739.3(1), c = 1272.5(1) pm, beta = 117.97(1)degrees, Z = 4, R-1 = 0.0361, L1c at -80 degrees C: space group P2(1) with a = 847.8(1), b = 1502.9(2), c = 981.5(2) pm, beta = 110.34(1)degrees, Z = 4, R-1 = 0.0376 and for 2 at - 80 degrees C: space group P1 with a = 1247.8(1), b = 1270.3(1), c 1387.5(1) pm, alpha = 84.32(1)degrees, beta = 84.71(1)degrees, gamma = 63.12(1)degrees, Z = 2, R-1 = 0.0539.

机译：4-氨基-5-甲基-2H-1,2,4-三唑-3（4H）-硫酮（AMTT，L1）与2-噻吩甲醛，水杨醛和2-硝基苯甲醛的甲醇反应生成相应的席夫-bases（L1a-c）。 L1与[（PPh3）（2）Cu] NO3在乙醇中的反应得到离子络合物[（PPh3）（2）Cu（L1）]（NO3EtOH）-Et-。（2）所有化合物均通过红外光谱，元素分析以及X射线衍射研究表征。 L1a在20°C时的晶体数据：空间群P2（1）/ n为439.6（2），b = 2074.0（9），c = 1112.8（4）pm，beta = 93.51（3）°，Z = 4 ，R-1 = 0.0406，-80摄氏度下的L1b：空间组P2（1）/ n，a = 1268.9（2），b = 739.3（1），c = 1272.5（1）pm，β= 117.97（1度，Z = 4，R-1 = 0.0361，-80°C时的L1c：空间群P2（1）/ n，a = 847.8（1），b = 1502.9（2），c = 981.5（2）pm ，beta = 110.34（1）度，Z = 4，R-1 = 0.0376和2在-80摄氏度下：空间群P1的a = 1247.8（1），b = 1270.3（1），c 1387.5（1） pm，alpha = 84.32（1）度，beta = 84.71（1）度，gamma = 63.12（1）度，Z = 2，R-1 = 0.0539。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2007年第3期|共5页
作者
Heshmatpour F; Ghassemzadeh M; Semsarha M; Neumuller B;
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正文语种 eng
中图分类化学;
关键词
1; 2; 4-triazole; Schiff bases; copper; crystal structures; X-RAY STRUCTURES; HETEROCYCLIC THIONES; SILVER(I) COMPLEXES; COPPER(I) COMPLEXES; LIGANDS; TRIPHENYLPHOSPHINE; AMTTO;

机译：1;2;4-三唑;席夫碱;铜;晶体结构;X射线结构;杂环亚硫基;银（I）络合物;铜（I）络合物;液体;三苯膦;AMTTO;

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1. Synthesis, characterization, and crystal structure of the new Schiff-bases derived from 1,2,4-triazole and the structure of [(PPh3)(2)Cu(AMTT)NO3 center dot EtOH (AMTT=4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione) [J] . Heshmatpour F, Ghassemzadeh M, Semsarha M, Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第3期

机译：1,2,4-三唑衍生的新席夫碱的合成，表征和晶体结构以及[（PPh3）（2）Cu（AMTT）NO3中心点EtOH（AMTT = 4-amino-5-甲基-2H-1,2,4-三唑-3（4H）-硫酮）
2. Synthesis, characterization and crystal structure of a silver(I) complex containing AMTT - (AMTT=4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione) [J] . Yazdanbakhsh M, Hakimi M, Heravi MM, Zeitschrift fur Anorganische und Allgemeine Chemie . 2006,第14期

机译：含AMTT-（AMTT = 4-氨基-5-甲基-2H-1,2,4-三唑-3（4H）-硫酮）的银（I）配合物的合成，表征和晶体结构
3. Synthesis, characterization and crystal structure of the dimeric silver(I) complex containing 4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione [J] . Sharafi T, Heravi MM, Ghassemzadeh M, Zeitschrift fur Anorganische und Allgemeine Chemie . 2005,第12期

机译：含4-氨基-5-甲基-2H-1,2,4-三唑-3（4H）-硫酮的二聚银（I）配合物的合成，表征和晶体结构
4. Synthesis and Characterization of Cu_2FeSnS_4 Semiconductor Nanocrystals with Zincblende Structure [C] . Xiaolu Liang, Xianhua Wei ICEEP 2012 . 2012

机译：锌尖结构Cu_2Fesns_4半导体纳米晶体的合成与表征
5. The crystal structures of three 3-methyl-1H-124-triazole-5-thiones including a second polymorph of 4-(E)-(5-bromo-2-hydroxybenzylidene)amino-3-methyl-1H-124-triazole-5(4H)-thione and a redetermination of 4-amino-3-methyl-1H-124-triazole-5(4H)-thione [O] . Padmanabha S. Manjula, Balladka K. Sarojini, Hemmige S. Yathirajan, 2015

机译：三种3-甲基-1H-124-三唑-5-硫酮的晶体结构包括4-（（E）-（5-溴-2-羟基亚苄基）氨基 -3-甲基的第二个多晶型物-1H-124-三唑-5（4H）-硫酮和4-氨基-3-甲基-1H-1124-三唑-5（4H）-硫酮的重新测定
6. The crystal structures of three 3-methyl-1H-1,2,4-triazole-5-thiones, including a second polymorph of 4-[(E)-(5-bromo-2-hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione and a redetermination of 4-amino-3-methyl-1H-1,2,4-triazole-5(4H)-thione [O] . Padmanabha S. Manjula, Balladka K. Sarojini, Hemmige S. Yathirajan, 2015

机译：三个3-甲基-1H-1,2,4-三唑-5-硫酮的晶体结构，包括4 - [（E） - （5-溴-2-羟基亚苄基）氨基] -3-甲基的第二多晶型-1H-1,2,4-三唑-5（4H） - 硫酮和4-氨基-3-甲基-1H-1,2,4-三唑-5（4H） - 硫酮的再次胺化

Synthesis, characterization, and crystal structure of the new Schiff-bases derived from 1,2,4-triazole and the structure of [(PPh3)(2)Cu(AMTT)NO3 center dot EtOH (AMTT=4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione)

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