Metal complexes of biologically important ligands, CVII. Formation of tris(pentamethylcyclopentadienyl-mu-L-prolinato-iridium) tris(trifluoromethanesulfonate) with chiral self recognition

Sunkel K.; Beck W.; Hoffmuller W.

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Metal complexes of biologically important ligands, CVII. Formation of tris(pentamethylcyclopentadienyl-mu-L-prolinato-iridium) tris(trifluoromethanesulfonate) with chiral self recognition

机译：具有生物重要性的配体CVII的金属配合物。具有手性自识别作用的三（五甲基环戊二烯基-mu-L-脯氨酰铱）三（三氟甲磺酸盐）的形成

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The structure of the title complex consists of [Ir-3(C5Me5)(3)(L-prolinate)(3)](3+) complex cations and CF3SO3- anions. Each iridium atom is coordinated in a distorted tetrahedral manner by one cyclopentadienyl group, two carboxylate O atoms and the prolinate N atom. The iridium atoms are bridged by the carboxylate groups. Each of the three stereogenic iridium atoms has the same (S) configuration, i. e. the trimerization of the [Ir(C5Me5)(L-prolinate)](+) fragment occurs with chiral self recognition. [References: 24]

机译：标题配合物的结构由[Ir-3（C5Me5）（3）（L-脯氨酸）（3）]（3+）配合物阳离子和CF3SO3-阴离子组成。每个铱原子以扭曲的四面体方式被一个环戊二烯基，两个羧基的O原子和脯氨酸的N原子配位。铱原子被羧酸酯基桥接。三个立体异构铱原子中的每一个都具有相同的（S）构型，即e。 [Ir（C5Me5）（L-脯氨酸）]（+）片段的三聚发生与手性自我识别。 [参考：24]

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |1998年第11期|共4页
作者
Sunkel K.; Beck W.; Hoffmuller W.;
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正文语种 eng
中图分类化学;
关键词
Pentamethylcyclopentadienyl; Iridium; Prolinate; Carboxylic-acid guests; Noncovalent pi-pi; Amino-acid; Molecular recognition; Crystal-structures; Ruthenium(ii); Rhodium(iii); Iridium(iii); Chemistry;

机译：五甲基环戊二烯基;铱;脯氨酸盐;羧酸客体;非共价pi-pi;氨基酸;分子识别;晶体结构;钌（ii）;铑（iii）;铱（iii）;化学;

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1. Metal complexes of biologically important ligands, CVII. Formation of tris(pentamethylcyclopentadienyl-mu-L-prolinato-iridium) tris(trifluoromethanesulfonate) with chiral self recognition [J] . Sunkel K., Beck W., Hoffmuller W. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 1998,第11期

机译：具有生物重要性的配体CVII的金属配合物。具有手性自识别作用的三（五甲基环戊二烯基-mu-L-脯氨酰铱）三（三氟甲磺酸盐）的形成
2. Chiral Recognition Among Tris(diimine)-Metal Complexes, 6, Racemic Compound Formation versus Conglomerate Formation with [M(bpy)_3](PF_6)_2 (M = Ni, Zn, Ru); Molecular and Crystal Structures [J] . Josef Breu, Holger Domel, Alexander Stoll European journal of inorganic chemistry . 2000,第11期

机译：Tris（diimine）-金属配合物6，外消旋化合物的形成与[[M（bpy）_3]（PF_6）_2（M = Ni，Zn，Ru）的团块形成之间的手性识别;分子和晶体结构
3. Chiral recognition among tris(diimine)-metal complexes. 9. Crystal structure prediction for the chiral molecular salt [Ru(bpy)(3)](PF6)(2) [J] . Huttner D, Breu J Zeitschrift fur Anorganische und Allgemeine Chemie . 2004,第13a14期

机译：三（二亚胺）-金属配合物之间的手性识别。 9.手性分子盐[Ru（bpy）（3）]（PF6）（2）的晶体结构预测
4. Synthesis of Metal Complexes with Tris(oxazolinylmethyl)amine Ligand and Their Catalytic Activity for Alkane Oxidation [C] . Jun Nakazawa, Junpei Endo, Naoki Jyozawa 日本化学会春季年会講演予稿集 . 2018

机译：三（恶唑啉基甲基）胺配体合成金属配合物及其烷烃氧化催化活性
5. Synthesis and reactivity of tungsten tris-(tri-tertbutyl) silyl imido complexes: Neutral and anionic derivatives, indirect evidence for the intermediacy of metal-alkane complexes in solution [D] . Schafer, Daniel Francis, II 1999

机译：钨三-（三叔丁基）甲硅烷基亚氨基配合物的合成和反应性：中性和阴离子衍生物，溶液中金属-烷烃配合物的间接证据
6. Complexes With Biologically Active Ligands. Part 71 Synthesis andFungitoxic Activity of Metal Complexes Containing 135-tris-(8-Hydroxyquinolino)- Trichlorocyclo-Triphosphazatriene [O] . Mihai Barboiu, Cornelia Guran, Ioana Jitaru, 1996

机译：具有生物活性配体的复合物。第71部分合成及含135-三（8-羟基喹啉）-三氯环三磷杂三烯的金属配合物的真菌毒性
7. Complexes With Biologically Active Ligands. Part 71 Synthesis and Fungitoxic Activity of Metal Complexes Containing 1,3,5-tris-(8-Hydroxyquinolino)- Trichlorocyclo-Triphosphazatriene [O] . Barboiu, Mihai, Guran, Cornelia, Jitaru, Ioana, 1996

机译：具有生物活性配体的复合物。第71部分合成及含1,3,5-三（8-羟基喹啉）-三氯环三磷杂三烯的金属配合物的真菌毒性
8. Chemistry of Di- and Tri-metal Complexes with Bridging Carbene or Carbyne Ligands. Part 47 [R] . Elliott, G. P., Howard, J. A., Mise, T., 1986

机译：具有桥接卡宾或卡宾配体的二金属和三金属配合物的化学。第47部分

Metal complexes of biologically important ligands, CVII. Formation of tris(pentamethylcyclopentadienyl-mu-L-prolinato-iridium) tris(trifluoromethanesulfonate) with chiral self recognition

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