On the crystal chemistry of tellurates containing Mn2+ in the cationic and anionic part of the crystal structure: (Mn2,4Cu0,6)TeO6, Ba2MnTeO6 and Pb(Mn0,5Te0,5)O-3 [German]

Wulff L.; Muller-Buschbaum H.; Wedel B.

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >On the crystal chemistry of tellurates containing Mn2+ in the cationic and anionic part of the crystal structure: (Mn2,4Cu0,6)TeO6, Ba2MnTeO6 and Pb(Mn0,5Te0,5)O-3 [German]

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On the crystal chemistry of tellurates containing Mn2+ in the cationic and anionic part of the crystal structure: (Mn2,4Cu0,6)TeO6, Ba2MnTeO6 and Pb(Mn0,5Te0,5)O-3 [German]

机译：关于在晶体结构的阳离子和阴离子部分中含有Mn2 +的碲酸盐的晶体化学：（Mn2,4Cu0,6）TeO6，Ba2MnTeO6和Pb（Mn0,5Te0,5）O-3 [德语]

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Single crystals of (Mn2.4Cu0.6)TeO6 (I), Ba2MnTeO6 (II) and Pb(Mn0.5Te0.5)O-3 (III) have been prepared by crystallization from fluxes. X-ray investigations led to rhombohedric symmetry (I): R (3) over tilde, (II): R (3) over tilde m with the trigonal lattice constants (I): a = 8.826(1), c = 10.687(2) Angstrom, Z = 2. (II): a = 5.817(8), c = 14.244(3) Angstrom, Z = 3. Compound (III) crystallizes with cubic symmetry P4 (3) over bar m, a = 4.045(3) Angstrom, Z = 1. (I) is the first example of a manganese(II) tellurate and belongs to the structure type of A(3)XO(6) compounds like (Mn2In)SbO6, Mn3WO6 and Ca3UO6. (II) exemplifies an ordered and (III) a disordered variation of the perovskites. [References: 20]

机译：（Mn2.4Cu0.6）TeO6（I），Ba2MnTeO6（II）和Pb（Mn0.5Te0.5）O-3（III）的单晶是通过从助熔剂中结晶而制得的。 X射线研究导致菱形对称（I）：波浪号上的R（3），（II）：波浪号m上的三角网格对称性（I）：a = 8.826（1），c = 10.687（ 2）埃，Z =2。（II）：a = 5.817（8），c = 14.244（3）埃，Z =3。化合物（III）在bar m处以立方对称P4（3）结晶，a = 4.045 （3）埃，Z =1。（I）是碲酸锰（II）的第一个例子，属于A（3）XO（6）化合物的结构类型，例如（Mn2In）SbO6，Mn3WO6和Ca3UO6。（II）举例说明钙钛矿的有序变化，（III）举例说明钙钛矿的无序变化。 [参考：20]

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |1998年第1期|共4页
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Wulff L.; Muller-Buschbaum H.; Wedel B.;
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1. On the crystal chemistry of tellurates containing Mn2+ in the cationic and anionic part of the crystal structure: (Mn2,4Cu0,6)TeO6, Ba2MnTeO6 and Pb(Mn0,5Te0,5)O-3 [German] [J] . Wulff L., Muller-Buschbaum H., Wedel B. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 1998,第1期

机译：关于在晶体结构的阳离子和阴离子部分中含有Mn2 +的碲酸盐的晶体化学：（Mn2,4Cu0,6）TeO6，Ba2MnTeO6和Pb（Mn0,5Te0,5）O-3 [德语]
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3. THE CRYSTAL STRUCTURE OF (AL0,5GA0,5)CUOASO4 - COPPER INTERMEDIATE BETWEEN PLANAR AND CLOSED COORDINATION [German] [J] . Moser P., Schuster HU., Jung W. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第11期

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8. Surface structures of Al-Pd-Mn and Al-Cu-Fe icosahedral quasicrystals [R] . Shen, Z. 1999

机译：al-pd-mn和al-Cu-Fe二十面体准晶的表面结构

On the crystal chemistry of tellurates containing Mn2+ in the cationic and anionic part of the crystal structure: (Mn2,4Cu0,6)TeO6, Ba2MnTeO6 and Pb(Mn0,5Te0,5)O-3 [German]

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