Structural characterization of N,NBis(diphenylphosphanyl)propylamine

Mayer T.; B?ttcher H.-C.

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Structural characterization of N,NBis(diphenylphosphanyl)propylamine

机译：N，NBis（二苯基膦基）丙胺的结构表征

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The synthesis and structural characterization of the Nsubstituted bis(diphenylphosphanyl)amine Ph2PN(R)PPh2 (R = n-propyl, 1) is reported. Single crystals of 1 grown from dichloromethane/acetonitrile have been analyzed by Xray crystallography. The crystallographic study revealed that the diphenylphosphanyl groups in 1 are staggered relative to the PNP backbone as observed for other closely related molecules.

机译：报道了N取代的双（二苯基膦基）胺Ph 2 PN（R）PPh 2（R ＝正丙基，1）的合成和结构表征。由X射线晶体学分析了从二氯甲烷/乙腈生长的1的单晶。晶体学研究表明，与其他密切相关的分子所观察到的相比，1中的二苯基膦烷基相对于PNP主链是交错的。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2012年第5期|共3页
作者
Mayer T.; B?ttcher H.-C.;
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正文语种 eng
中图分类化学;
关键词
Diphosphanes; N-Substituted Bis(phosphanyl)amines; Organophosphorus Ligands; Phosphorus; X-Ray Diffraction;

机译：二膦烷;N-取代的双（膦酰基）胺;有机磷配体;磷;X射线衍射;

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1. Structural characterization of N,NBis(diphenylphosphanyl)propylamine [J] . Mayer T., B?ttcher H.-C. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2012,第5期

机译：N，NBis（二苯基膦基）丙胺的结构表征
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Structural characterization of N,NBis(diphenylphosphanyl)propylamine

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