Syntheses, single-crystal structure determination, and Raman spectra of Rb[C(CN)(3)] and Cs[C(CN)(3)]

Reckeweg Olaf; Schulz Armin; DiSalvo Francis J.

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Syntheses, single-crystal structure determination, and Raman spectra of Rb[C(CN)(3)] and Cs[C(CN)(3)]

机译：Rb [C（CN）（3）]和Cs [C（CN）（3）]的合成，单晶结构确定和拉曼光谱

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Extracting residues of an aqueous solutions containing equimolar amounts of K[C(CN)(3)] and RbF or CsF, respectively, with absolute ethanol, yields triangular, transparent colorless crystals of Rb[C(CN)(3)] and Cs[C(CN)(3)] after the ethanol was allowed to evaporate. The compounds are isotypic and crystallize isopointal to calcite in space group R<(3over bar>c (no. 167) with the cell parameters a = 809.9(1) and c = 1461.3(3) pm and a = 843.29(9) and c = 1459.9(2) pm, respectively. Single crystals were used to record the Raman spectra of the title compounds.

机译：用无水乙醇分别提取等摩尔量的K [C（CN）（3）]和RbF或CsF的水溶液中的残留物，得到Rb [C（CN）（3）]和Cs的三角形透明无色晶体使乙醇蒸发后的[C（CN）（3）]。这些化合物是同型的，并且在空间群R <（3 over bar> c（no。167））中等位结晶为方解石，其电池参数为a = 809.9（1）和c = 1461.3（3）pm，a = 843.29（9）和c分别为1459.9（2）pm。使用单晶记录标题化合物的拉曼光谱。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2015年第2期|共4页
作者
Reckeweg Olaf; Schulz Armin; DiSalvo Francis J.;
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正文语种 eng
中图分类化学;
关键词
alkali metal; caesium; Raman spectrum; rubidium; tricyanomethanide;

机译：碱金属;铯;拉曼光谱;rub;三氰胺;

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Syntheses, single-crystal structure determination, and Raman spectra of Rb[C(CN)(3)] and Cs[C(CN)(3)]

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