RE4B4O11F2 (RE = Sm, Tb, Ho, Er): four new rare earth fluoride borates isotypic to Gd4B4O11F2

Glatzle Matthias; Huppertz Hubert

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >RE4B4O11F2 (RE = Sm, Tb, Ho, Er): four new rare earth fluoride borates isotypic to Gd4B4O11F2

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RE4B4O11F2 (RE = Sm, Tb, Ho, Er): four new rare earth fluoride borates isotypic to Gd4B4O11F2

机译：RE4B4O11F2（RE = Sm，Tb，Ho，Er）：与Gd4B4O11F2同型的四个新的氟化硼硼酸盐

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The rare earth fluoride borates RE4B4O11F2 (RE = Sm, Tb, Ho, Er) were synthesized in a Walker-type multianvil apparatus from the corresponding rare earth oxides and fluorides with boron oxide. Sm4B4O11F2 was obtained under high-pressure/high-temperature conditions of 6 GPa/1100 degrees C, Tb4B4O11F2 at 7.5 GPa/1200 degrees C, and Ho4B4O11F2 and Er4B4O11F2 at 9.5 GPa/1300 degrees C. The single-crystal structure determinations showed that all compounds are isotypic to the known rare earth fluoride borates RE4B4O11F2 (RE = Pr, Nd, Eu, Gd, Dy). They crystallize in the monoclinic space group C-2/c (Z = 4). The structure is built up from BO4 tetrahedra as well as BO3 groups connected via common corners. Here, we report about the crystallographic characterization of these new compounds in comparison to the isotypic phases RE4B4O11F2 (RE = Pr, Nd, Eu, Gd, Dy).

机译：在Walker型多砧装置中，由相应的稀土氧化物和氟化物与氧化硼合成稀土氟化硼硼酸盐RE4B4O11F2（RE = Sm，Tb，Ho，Er）。 Sm4B4O11F2在6 GPa / 1100摄氏度的高压/高温条件下，7.5 GPa / 1200摄氏度的Tb4B4O11F2和Ho4B4O11F2和Er4B4O11F2在9.5 GPa / 1300摄氏度的条件下获得。单晶结构测定表明，所有晶体这些化合物与已知的稀土氟化硼硼酸盐RE4B4O11F2（RE = Pr，Nd，Eu，Gd，Dy）同型。它们在单斜空间群C-2 / c（Z = 4）中结晶。该结构由BO4四面体以及通过公共角连接的BO3组构成。在这里，我们报道了与同型相RE4B4O11F2（RE = Pr，Nd，Eu，Gd，Dy）相比，这些新化合物的晶体学表征。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2016年第11期|共9页
作者
Glatzle Matthias; Huppertz Hubert;
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正文语种 eng
中图分类化学;
关键词
borate; crystal structure; fluoride; high pressure; rare earth;

机译：硼酸盐;晶体结构;氟化物;高压;稀土;

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1. RE4B4O11F2 (RE = Sm, Tb, Ho, Er): four new rare earth fluoride borates isotypic to Gd4B4O11F2 [J] . Glatzle Matthias, Huppertz Hubert Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2016,第11期

机译：RE4B4O11F2（RE = Sm，Tb，Ho，Er）：与Gd4B4O11F2同型的四个新的氟化硼硼酸盐
2. beta-RE1-xBixB3O6 (RE = Sm, Eu, Gd, Tb, Dy, Ho, Er, Y): Bi3+ Substitution Induced Formation of Metastable Rare Earth Borates at Ambient Pressure [J] . Sun Xiaorui, Yang Ruirui, Song Rixiang, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第18期

机译：beta-RE1-xBixB3O6（RE = Sm，Eu，Gd，Tb，Dy，Ho，Er，Y）：Bi3 +取代在环境压力下诱导形成亚稳态稀土硼酸盐
3. beta-RE1-xBixB3O6 (RE = Sm, Eu, Gd, Tb, Dy, Ho, Er, Y): Bi3+ Substitution Induced Formation of Metastable Rare Earth Borates at Ambient Pressure [J] . Sun Xiaorui, Yang Ruirui, Song Rixiang, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第18期

机译：beta-RE1-xBixB3O6（RE = Sm，Eu，Gd，Tb，Dy，Ho，Er，Y）：Bi3 +取代在环境压力下诱导形成亚稳态稀土硼酸盐
4. UV-visible Faraday rotators based on rare-earth fluoride single crystals: LiREF_4 (RE=Tb, Dy, Ho, Er and Yb), PrF_3 and CeF_3 [C] . Valentyn Vasyliev, Encarnacion G.Villora, Masaru Nakamura Electronics Division Meeting of the Ceramic Society of Japan . 2014

机译：基于稀土氟化物单晶的UV可见法拉第转子：Liref_4（Re = TB，Dy，Ho，ER和YB），PRF_3和CEF_3
5. Experimental and thermodynamic investigation of RE-Mg-Zn (RE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) systems [D] . Zhu, Zhijun. 2015

机译：RE-Mg-Zn（RE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Lu）系统的实验和热力学研究
6. Electrochemical Recovery and Behaviors of Rare Earth (La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm and Yb) Ions on Ni Sheets [O] . Min Hee Joo, So Jeong Park, Sung Min Hong, 2020

机译：稀土电化学回收和行为（LaCePrNdSm欧盟GdTbDyHoERTm和Yb）离子在Ni纸上
7. Magnetism in the KBaRE(BO3)2 (RE=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) series: materials with a triangular rare earth lattice [O] . Sanders, M. B., Cevallos, F. A., Cava, R. J. 2016

机译：KBaRE（BO3）2中的磁性（RE = sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu）系列：具有三角形稀土晶格的材料
8. DETERMINATION OF RARE EARTHS AND FLUORIDES IN RARE EARTH FLUORIDES [R] . L. P. Rigdon, W. E. Sunderland 1968

机译：稀土氟稀土中稀土和氟的测定

RE4B4O11F2 (RE = Sm, Tb, Ho, Er): four new rare earth fluoride borates isotypic to Gd4B4O11F2

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