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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A novel 3D Cd(II) metal-organic framework with an unprecedented (5,6)-connected topology based on isophthalate and 2-(3-pyridyl)imidazo[4,5-f] 1,10-phenanthroline
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A novel 3D Cd(II) metal-organic framework with an unprecedented (5,6)-connected topology based on isophthalate and 2-(3-pyridyl)imidazo[4,5-f] 1,10-phenanthroline

机译:基于间苯二甲酸和2-(3-吡啶基)咪唑并[4,5-f] 1,10-菲咯啉的具有前所未有的(5,6)连接拓扑的新型3D Cd(II)金属-有机骨架

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摘要

A novel three dimensional cadmium metal-organic framework [Cd-3(1,3-BDC)(3)(PIP)(2)]center dot 8H(2)O (1) with an unprecedented (5,6)-connected topology has been synthesized from the hydrothermal reaction of cadmium(II) nitrate with the mixed ligands isophthalate acid (1,3-H2BDC) and 2-(3-pyridyl) imidazo[4,5-f]1,10-phenanthroline (PIP). Its fluorescence property and thermal stability were investigated.
机译:新型三维镉金属有机框架[Cd-3(1,3-BDC)(3)(PIP)(2)]中心点8H(2)O(1)具有前所未有的(5,6)连接由硝酸镉(II)与间苯二酸(1,3-H2BDC)和2-(3-吡啶基)咪唑并[4,5-f] 1,10-菲咯啉(PIP)的混合配体水热反应合成了拓扑结构)。研究了其荧光性质和热稳定性。

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