Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

Raynal M; Liu XH; Pattacini R; Vallee C; Olivier-Bourbigou H; Braunstein P

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Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

机译：前所未有的古巴型银簇，具有新型次膦酸酯官能化的N-杂环卡宾配体

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摘要

A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag2I2 faces.

机译：合成了一种新型的异双功能次膦酸酯亚氨酸咪唑鎓盐，并与Ag（I）反应，得到了一种具有两个P-NHC配体的不寻常的四银古巴型簇，它们桥接在相对的Ag2I2面的Ag（I）中心之间。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第35期|共6页
作者
Raynal M; Liu XH; Pattacini R; Vallee C; Olivier-Bourbigou H; Braunstein P;
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正文语种 eng
中图分类化学;
关键词
CROSS-COUPLING REACTIONS; COORDINATION CHEMISTRY; PALLADIUM COMPLEXES;

机译：交叉偶联反应;配位化学;钯络合物;

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1. Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand [J] . Raynal M, Liu XH, Pattacini R, Dalton transactions: An international journal of inorganic chemistry . 2009,第35期

机译：前所未有的古巴型银簇，具有新型次膦酸酯官能化的N-杂环卡宾配体
2. Unprecedented large temperature dependence of silver(I)-silver(I) distances in some N-heterocyclic carbene silver(I) complex salts [J] . Kriechbaum M., H?lbling J., Stammler H.-G., Organometallics . 2013,第10期

机译：一些N杂环卡宾银（I）络合物盐中银（I）-银（I）距离的前所未有的大温度依赖性
3. Silver(I)-N-heterocyclic carbene complexes of nitrile-functionalized imidazol-2-ylidene ligands as anticancer agents [J] . Rosenani A. Haque, Srinivasa Budagumpi, H. Zetty ZuJikha Inorganic Chemistry Communications . 2014,第Null期

机译：腈官能化咪唑-2-亚烷基配体作为抗癌剂的银（I）-N-杂环卡宾配合物
4. (Invited) Ligands in Electroreduction of CO_2: N-Heterocyclic Carbene-Capped Polymers to Promote Catalytic Efficiency [C] . Jie He Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：（诱人的）配体在Co_2：正杂环封端的聚合物中的电气控制，以促进催化效率
5. Catalytic C-H Bond Functionalization by Nickel(0) N-Heterocyclic Carbene Complexes: Influence of Ligand Sterics on Selective Silylation [D] . Elsby, Matthew Ryan. 2017

机译：镍（0）N-杂环碳烯络合物的催化C-H键官能化：配体的立体异构体对选择性硅烷化的影响
6. Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands [O] . Dirk Meyer, Thomas Strassner 2016

机译：具有嘧啶官能化的N-杂环卡宾配体的甲基钯配合物
7. Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters [O] . Ramírez, Jesus, Corberán, Rosa, Sanau Torrecilla, Mercedes, 2005

机译：N-杂环卡宾银络合物用于催化制备1,2-双（硼酸酯）的前所未有的应用

Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

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