Coordinating ability of anions and solvents towards transition metals and lanthanides

Díaz-Torres R.; Alvarez S.

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Coordinating ability of anions and solvents towards transition metals and lanthanides

机译：阴离子和溶剂对过渡金属和镧系元素的配位能力

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A scale that attempts to quantify the weakly coordinating character of a variety of solvents and anions is presented. For each group (solvent or anion), a coordinating ability index has been calculated, based on the probability of it being coordinated in the presence of a transition metal atom, compared to the probability of finding it as a solvation molecule or as non-coordinating counterion in a crystal structure. The corresponding index is also defined for the same groups in the presence of lanthanides, and the similarities and differences are discussed.

机译：提出了一种试图量化各种溶剂和阴离子的弱配位特征的量表。对于每个基团（溶剂或阴离子），已经根据在过渡金属原子存在下被配位的概率与发现其为溶剂化分子或不配位的概率进行了计算，得出了配位能力指数晶体结构中的抗衡离子。还针对镧系元素存在下的相同基团定义了相应的索引，并讨论了相似性和差异性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第40期|共9页
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Díaz-Torres R.; Alvarez S.;
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1. Coordinating ability of anions and solvents towards transition metals and lanthanides [J] . Díaz-Torres R., Alvarez S. Dalton transactions: An international journal of inorganic chemistry . 2011,第40期

机译：阴离子和溶剂对过渡金属和镧系元素的配位能力
2. Anion photoelectron spectroscopy of transition metal- and lanthanide metal-silicon clusters: MSin- (n=6-20) [J] . Koyasu K, Atobe J, Furuse S, The Journal of Chemical Physics . 2008,第21期

机译：过渡金属和镧系元素金属-硅簇的阴离子光电子能谱：MSin-（n = 6-20）
3. Lanthanide metal-organic frameworks as multifunctional luminescent sensor for detecting cations, anions and organic solvent molecules in aqueous solution [J] . Feng Liu, Wei Gao, Peng Li, Journal of Solid State Chemistry . 2017,第期

机译：镧系金属 - 有机框架作为多官能发光传感器，用于检测水溶液中的阳离子，阴离子和有机溶剂分子
4. Specially Functionalised Ligands and Coordinating Supports which Facilitate Dissolution of Catalytic Transition Metal Species in Non-Polar "Green" Solvents, such as ScCO_2 [C] . M. Herbert, A. Galindo, F. Montilla European Meeting on Supercritical Fluids . 2008

机译：特殊功能化配体和协调支持，其促进催化过渡金属种类在非极性“绿色”溶剂中的溶解，例如SCCO_2
5. Synthesis and characterization of divalent lanthanide (lanthanide(2+) = samarium, europium, ytterbium) coordination complexes with boron hydride and transition metal carbonyl anions; the formation of metallic films and metal borides from complex precursors. [D] . White, James Paul, III. 1990

机译：具有氢化硼和过渡金属羰基阴离子的二价镧系元素（镧系元素（2 +）= ,、 euro，）的合成与表征；由复杂的前体形成金属膜和金属硼化物。
6. New Carbon Nanofiber Composite Materials Containing Lanthanides and Transition Metals Based on Electrospun Polyacrylonitrile for High Temperature Polymer Electrolyte Membrane Fuel Cell Cathodes [O] . Igor I. Ponomarev, Kirill M. Skupov, Olga M. Zhigalina, 2020

机译：基于静电纺聚丙烯腈的含镧系元素和过渡金属的新型碳纳米纤维复合材料用于高温聚合物电解质膜燃料电池阴极
7. Lanthanide-Transition Metal Carbonyl Complexes: Condensation of Solvent-Separated Ion-Pair Compounds into Extended Structures [O] . -1

机译：镧系元素过渡金属羰基配合物：溶剂分离离子对化合物的缩合到延长的结构中

Coordinating ability of anions and solvents towards transition metals and lanthanides

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