Isolation and reactivity of an unusually stable organoselenenyl azide

Srivastava K.; Chakraborty T.; Singh H.B.; Singh U.P.; Butcher R.J.

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Isolation and reactivity of an unusually stable organoselenenyl azide

机译：异常稳定的有机硒烯叠氮化物的分离和反应性

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The stabilities of a series of isolated covalent selenium(ii) azides such as [2-[1-(3,5-dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole] selenium azide (2a), [2-(4,4-dimethyl-2-oxazolinyl)phenyl]selenenyl azide (3a), [o-(2,6-diisopropylphenyl-iminomethinyl)phenyl]selenenyl azide (4a), [o-(R)-(methylbenzyliminomethinyl)phenyl]selenenyl azide (5a) and o-formylphenylselenenyl azide (6a) are rationalized; also the reactivity of first room temperature stable azide (2a) toward 1,3-cycloaddition has been explored.

机译：一系列分离的共价硒（ii）叠氮化物（例如[2- [1-（3,5-二甲基苯基）-2-萘基] -4,5-二氢-4,4-二甲基恶唑]叠氮化硒（2a ），[2-（4,4-二甲基-2-恶唑啉基）苯基]硒烯叠氮化物（3a），[邻-（2,6-二异丙基苯基-亚氨基次甲基）苯基]硒烯叠氮化物（4a），[o-（R） -（甲基苄基亚氨基次甲基）苯基]硒烯叠氮化物（5a）和邻甲酰基苯基硒烯叠氮化物（6a）被合理化;还研究了第一室温稳定的叠氮化物（2a）对1，3-环加成的反应性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2010年第42期|共5页
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Srivastava K.; Chakraborty T.; Singh H.B.; Singh U.P.; Butcher R.J.;
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Isolation and reactivity of an unusually stable organoselenenyl azide

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