Recent progress in olefin polymerization catalyzed by transition metal complexes: new catalysts and new reactions

Takeuchi D

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Recent progress in olefin polymerization catalyzed by transition metal complexes: new catalysts and new reactions

机译：过渡金属配合物催化烯烃聚合的最新进展：新催化剂和新反应

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A number of transition metal catalysts including early and late transition metals have been investigated for olefin polymerization and copolymerization. Progress of the field in this decade is reviewed, and important topics among them such as binary catalysts and polymerization of new monomers are described in detail. Our recent results on the polymerization of olefins having cycloalkenes and non-conjugated dienes using late transition metal complexes are also mentioned.

机译：为了烯烃聚合和共聚，已经研究了许多过渡金属催化剂，包括早期和晚期过渡金属。回顾了该领域十年的进展，并详细描述了其中的重要主题，例如二元催化剂和新单体的聚合。还提到了我们最近的关于使用后期过渡金属配合物聚合具有环烯烃和非共轭二烯的烯烃的结果。

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《Dalton transactions: An international journal of inorganic chemistry》 |2010年第2期|共18页
作者
Takeuchi D;
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正文语种 eng
中图分类化学;
关键词
ZIEGLER-NATTA POLYMERIZATION; NONBRIDGED HALF-TITANOCENES; NEUTRAL NICKEL(II) COMPLEXES; IMINE CHELATE LIGANDS; SINGLE-SITE CATALYSTS; MOLECULAR-WEIGHT POLYETHYLENE; ONE-POT SYNTHESIS; TRIDENTATE PYRIDINE-2; 6-BIS(ARYLOXIDE) LIGANDS; SYNDIOSPECIFIC LIVING POLYMERIZATION; AMINE BIS(PHENOLATE) TITANIUM;

机译：Ziegler-nata聚合;非桥接半钛茂;中性镍（II）络合物;亚胺螯合剂;单部位催化剂;分子量聚乙烯;一键合成;对苯二甲酸二吡啶二吡啶;6-二吡啶活性聚合;氨基双酚（钛）钛;

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1. Recent progress in olefin polymerization catalyzed by transition metal complexes: new catalysts and new reactions [J] . Takeuchi D Dalton transactions: An international journal of inorganic chemistry . 2010,第2期

机译：过渡金属配合物催化烯烃聚合的最新进展：新催化剂和新反应
2. Complexes of Transition Metals With Lewis Bases As Precursors of Olefin Polymerization Catalysts. Part I. Advance In Computer-Assisted Modeling of polymerization Catalyst Structure [J] . ZYGMUNT FLISAK, KRZYSZTOF SZCZEGOT Polimery . 2001,第5期

机译：具有路易斯碱的过渡金属配合物作为烯烃聚合催化剂的前体。第一部分。聚合催化剂结构的计算机辅助建模的进展
3. Complexes of transition metals with Lewis bases as precursors of olefin polymerisation catalysts. 1. Progress in computer-assisted modelling of the structure of a polymerisation catalyst [J] . Z. Flisak, K. Szczegot International Polymer Science and Technology . 2001,第12期

机译：过渡金属与路易斯碱的络合物作为烯烃聚合催化剂的前体。 1.聚合催化剂结构的计算机辅助建模研究进展
4. O'NX TITANIUM COMPLEXES-CATALYZED COPOLYMERIZATION OF ETHYLENE WITH FUNCTIONALIZED OLEFINS AND ITS APPLICATION AS A SUPPORTING MATERIAL IN CATALYTIC YLIDE REACTIONS [C] . Cong Wang, Xiao-Hong Yang, Xiu-Li Sun, International symposium on polymer chemistry : Preprints. . 2010

机译：O'NX钛与功能化烯烃的钛络合物催化的乙烯共聚合及其在催化乙炔反应中的应用
5. Organometallic Reaction Mechanisms: Olefin Polymerization Catalysis and Carbon-Hydrogen Bond Activation by Early Transition Metal Bisphenolate Complexes and Protonolysis of Bipyrimidine Platinum Methyl Complexes. [D] . Golisz, Suzanne R. 2010

机译：有机金属反应机理：早期过渡金属双酚盐配合物的烯烃聚合催化和碳氢键活化以及联嘧啶铂甲基配合物的质子分解。
6. Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts Non-Thermally Triggered Hydrosilylation Reactions and Industrial Applications [O] . Robin J. Hofmann, Matea Vlatković, Frank Wiesbrock 2017

机译：高分子科学中的氢化硅烷化五十年：低成本过渡金属和无金属催化剂非热引发的氢化硅烷化反应和工业应用的当前趋势的回顾
7. The effect of ligand array on stereocontrol and molecular weight in metallocene-catalyzed alpha-olefin polymerization and (PNP)CrPh3 complexes as well-defined ethylene trimerization catalysts [O] . Schofer Susan Jessica 2004

机译：配体阵列对茂金属催化α-烯烃聚合和（pNp）Crph3配合物中立体控制和分子量的影响，定义为乙烯三聚催化剂
8. Synthetic and mechanistic investigation of olefin polymerization catalyzed by early transition metal compounds. Progress report, Second year, 1 April 1992--31 March 1992 [R] . Bercaw, J. E. 1993

机译：早期过渡金属化合物催化烯烃聚合的合成和机理研究。进度报告，第二年，1992年4月1日至1992年3月31日

Recent progress in olefin polymerization catalyzed by transition metal complexes: new catalysts and new reactions

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