Synthesis, structures and electrochemistry studies of 2Fe2S-Fe(ii)(S-2N) _2 models for H-cluster of [FeFe]-hydrogenase

Hu M.-Q.; Wen H.-M.; Ma C.-B.; Li N.; Yan Q.-Y.; Chen H.; Chen C.-N.

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Synthesis, structures and electrochemistry studies of 2Fe2S-Fe(ii)(S-2N) _2 models for H-cluster of [FeFe]-hydrogenase

机译：[FeFe]-加氢酶H簇的2Fe2S-Fe（ii）（S-2N）_2模型的合成，结构和电化学研究

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A series of model complexes [(μ-pdt)Fe_2(CO)_5] _2M(sip)_2 (M = Fe, Ni) were synthesized as H-cluster analogues of [FeFe]-hydrogenase. Their electrochemical behaviours were investigated and it is proposed that the bridging metal bis(tris-chelate) groups act as electron transfer sites in theses mimics.

机译：合成了一系列模型配合物[（μ-pdt）Fe_2（CO）_5] _2M（sip）_2（M = Fe，Ni），作为[FeFe]-加氢酶的H-簇类似物。研究了它们的电化学行为，并提出在这些模拟物中桥联的金属双（三螯合物）基团充当电子转移位点。

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《Dalton transactions: An international journal of inorganic chemistry》 |2010年第40期|共3页
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Hu M.-Q.; Wen H.-M.; Ma C.-B.; Li N.; Yan Q.-Y.; Chen H.; Chen C.-N.;
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机译：[FeFe]-加氢酶H簇的2Fe2S-Fe（ii）（S-2N）_2模型的合成，结构和电化学研究
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Synthesis, structures and electrochemistry studies of 2Fe2S-Fe(ii)(S-2N) _2 models for H-cluster of [FeFe]-hydrogenase

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